Olefin Amine (OLA) Reagents for the Synthesis of Bridged Bicyclic and Spirocyclic Saturated N‑Heterocycles by Catalytic Hydrogen Atom Transfer (HAT) Reactions

Spiro- and bridged bicyclic structures are in demand for their sp3-rich frameworks that offer unique physiochemical properties and precisely positioned substituent groups. In order to rapidly access such molecules in a cross-coupling fashion we describe olefin amine (OLA) reagents for the transforma...

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Veröffentlicht in:	Journal of the American Chemical Society 2019-06, Vol.141 (24), p.9739-9745
Hauptverfasser:	Wang, Ya-Yi, Bode, Jeffrey W
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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