The Persistent Radical Effect in Organic Synthesis

Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the selective cross‐coupling of two different radicals is challenging and not a synthetically valuable transformation. However, if the radicals have different lifetimes and if they are generated at equal rates, cr...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-01, Vol.59 (1), p.74-108
Hauptverfasser:	Leifert, Dirk, Studer, Armido
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis Computer simulation Coordination compounds Couplings Cross coupling kinetics Metal complexes Organic chemistry Radicals Selectivity transition metals
Online-Zugang:	Volltext
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