Hydrous ferric oxide nanoparticles hosted porous polyethersulfone adsorptive membrane: chromium (VI) adsorptive studies and its applicability for water/wastewater treatment

In this present study, adsorptive membranes for Cr(VI) ion removal were prepared by blending polyethersulfone (PES) with hydrous ferric oxide (HFO) nanoparticles (NPs). The effects of HFO NPs to PES weight ratio (0–1.5) on the physicochemical properties of the resultant HFO/PES adsorptive membranes...

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Veröffentlicht in:Environmental science and pollution research international 2019-07, Vol.26 (20), p.20386-20399
Hauptverfasser: Abdullah, Norfadhilatuladha, Yusof, Norhaniza, Abu Shah, Muhammad Hafiz, Wan Ikhsan, Syarifah Nazirah, Ng, Zhi-Chien, Maji, Subrata, Lau, Woei Jye, Jaafar, Juhana, Ismail, Ahmad Fauzi, Ariga, Katsuhiko
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container_issue 20
container_start_page 20386
container_title Environmental science and pollution research international
container_volume 26
creator Abdullah, Norfadhilatuladha
Yusof, Norhaniza
Abu Shah, Muhammad Hafiz
Wan Ikhsan, Syarifah Nazirah
Ng, Zhi-Chien
Maji, Subrata
Lau, Woei Jye
Jaafar, Juhana
Ismail, Ahmad Fauzi
Ariga, Katsuhiko
description In this present study, adsorptive membranes for Cr(VI) ion removal were prepared by blending polyethersulfone (PES) with hydrous ferric oxide (HFO) nanoparticles (NPs). The effects of HFO NPs to PES weight ratio (0–1.5) on the physicochemical properties of the resultant HFO/PES adsorptive membranes were investigated with respect to the surface chemistry and roughness as well as structural morphologies using different analytical instruments. The adsorptive performance of the HFO NPs/PES membranes was studied via batch adsorption experiments under various conditions by varying solution pH, initial concentration of Cr(VI), and contact time. The results showed that the membrane made of HFO/PES at a weight ratio of 1.0 exhibited the highest adsorption capacity which is 13.5 mg/g. Isotherm and kinetic studies revealed that the mechanism is best fitted to the Langmuir model and pseudo-second-order model. For filtration of Cr(VI), the best promising membranes showed improved water flux (629.3 L/m 2  h) with Cr(VI) ion removal of 75%. More importantly, the newly developed membrane maintained the Cr(VI) concentration below the maximum contamination level (MCL) for up to 9 h.
doi_str_mv 10.1007/s11356-019-05208-9
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The effects of HFO NPs to PES weight ratio (0–1.5) on the physicochemical properties of the resultant HFO/PES adsorptive membranes were investigated with respect to the surface chemistry and roughness as well as structural morphologies using different analytical instruments. The adsorptive performance of the HFO NPs/PES membranes was studied via batch adsorption experiments under various conditions by varying solution pH, initial concentration of Cr(VI), and contact time. The results showed that the membrane made of HFO/PES at a weight ratio of 1.0 exhibited the highest adsorption capacity which is 13.5 mg/g. Isotherm and kinetic studies revealed that the mechanism is best fitted to the Langmuir model and pseudo-second-order model. For filtration of Cr(VI), the best promising membranes showed improved water flux (629.3 L/m 2  h) with Cr(VI) ion removal of 75%. 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subjects Adsorption
Adsorptivity
Aquatic Pollution
Atmospheric Protection/Air Quality Control/Air Pollution
Blending effects
Chromium
Contamination
Earth and Environmental Science
Ecotoxicology
Environment
Environmental Chemistry
Environmental Health
Environmental science
Ferric oxide
Hematite
Membranes
Morphology
Nanoparticles
Organic chemistry
Physicochemical properties
Polyethersulfones
Research Article
Surface chemistry
Waste Water Technology
Wastewater treatment
Water Management
Water Pollution Control
Water purification
Water treatment
Weight
title Hydrous ferric oxide nanoparticles hosted porous polyethersulfone adsorptive membrane: chromium (VI) adsorptive studies and its applicability for water/wastewater treatment
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