Base-promoted regiodivergent allylation of N-acylhydrazones with Morita-Baylis-Hillman carbonates by tuning the catalyst

Base-promoted regiodivergent allylation of N-acylhydrazones with Morita-Baylis-Hillman carbonates by tuning the catalyst

A regiodivergent allylation of N-acylhydrazones with Morita-Baylis-Hillman (MBH) carbonates has been developed, providing α- or γ-allylated products in excellent yields by using different catalysts. The nature of the base catalyst plays a pivotal role in controlling the reaction pathway, allowing re...

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Veröffentlicht in:Organic & biomolecular chemistry 2019-05, Vol.17 (21), p.5283-5293
Hauptverfasser: Sun, Fang, Yin, Tingrui, Feng, Anni, Hu, Yong, Yu, Chenxia, Li, Tuanjie, Yao, Changsheng
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container_end_page 5293
container_issue 21
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container_title Organic & biomolecular chemistry
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creator Sun, Fang
Yin, Tingrui
Feng, Anni
Hu, Yong
Yu, Chenxia
Li, Tuanjie
Yao, Changsheng
description A regiodivergent allylation of N-acylhydrazones with Morita-Baylis-Hillman (MBH) carbonates has been developed, providing α- or γ-allylated products in excellent yields by using different catalysts. The nature of the base catalyst plays a pivotal role in controlling the reaction pathway, allowing regiospecific access to diverse allylic substituted target compounds from identical substrates.
doi_str_mv 10.1039/c9ob00194h
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title Base-promoted regiodivergent allylation of N-acylhydrazones with Morita-Baylis-Hillman carbonates by tuning the catalyst
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