Al/P‐ and Ga/P‐Based Frustrated Lewis Pairs and Electronically Unsaturated Substrates: Ring Cleavage and Ring Closure, C−C and C−N Bond Formation

Al/P‐ and Ga/P‐based frustrated Lewis pairs (FLPs) reacted with an azirine under mild conditions under cleavage of the heterocycle on two different positions. Opening of the C−C bond yielded an unusual nitrile–ylide adduct in which a C−N moiety coordinated to the FLP backbone. Cleavage of a C−N bond...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemistry : a European journal 2019-07, Vol.25 (39), p.9315-9325
Hauptverfasser:	Pleschka, Damian, Uebing, Marten, Lange, Merten, Hepp, Alexander, Wübker, Anna‐Lena, Hansen, Michael Ryan, Würthwein, Ernst‐Ulrich, Uhl, Werner
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic properties Bonding Chemistry Cleavage C−C bond formation C−N bond formation frustrated Lewis pairs methylene phosphonium cations Migration ring cleavage ring closure Shielding Substrates YneS protein
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!