Design Strategies for Vanadium‐based Aqueous Zinc‐Ion Batteries

Aqueous zinc‐ion batteries (ZIBs) are considered promising energy storage devices for large‐scale energy storage systems as a consequence of their safety benefits and low cost. In recent years, various vanadium‐based compounds have been widely developed to serve as the cathodes of aqueous ZIBs becau...

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Veröffentlicht in:Angewandte Chemie International Edition 2019-11, Vol.58 (46), p.16358-16367
Hauptverfasser: Wan, Fang, Niu, Zhiqiang
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Niu, Zhiqiang
description Aqueous zinc‐ion batteries (ZIBs) are considered promising energy storage devices for large‐scale energy storage systems as a consequence of their safety benefits and low cost. In recent years, various vanadium‐based compounds have been widely developed to serve as the cathodes of aqueous ZIBs because of their low cost and high theoretical capacity. Furthermore, different energy storage mechanisms are observed in ZIBs based on vanadium‐based cathodes. In this Minireview, we present a comprehensive overview of the energy storage mechanisms and structural features of various vanadium‐based cathodes in ZIBs. Furthermore, we discuss strategies for improving the electrochemical performance of vanadium‐based cathodes; including, insertion of metal ions, adjustment of structural water, selection of conductive additives, and optimization of electrolytes. Finally, this Minireview offers insight into potential future directions in the design of innovative vanadium‐based electrode materials. Vanadium‐based compounds are widely implemented as cathodes for aqueous zinc‐ion batteries (ZIBs) because of their low cost and high theoretical capacity. This Minireview presents a comprehensive overview of the energy storage mechanisms and structural features of various vanadium‐based cathodes in ZIBs. Strategies for improving the electrochemical performance of vanadium‐based cathodes are discussed.
doi_str_mv 10.1002/anie.201903941
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In recent years, various vanadium‐based compounds have been widely developed to serve as the cathodes of aqueous ZIBs because of their low cost and high theoretical capacity. Furthermore, different energy storage mechanisms are observed in ZIBs based on vanadium‐based cathodes. In this Minireview, we present a comprehensive overview of the energy storage mechanisms and structural features of various vanadium‐based cathodes in ZIBs. Furthermore, we discuss strategies for improving the electrochemical performance of vanadium‐based cathodes; including, insertion of metal ions, adjustment of structural water, selection of conductive additives, and optimization of electrolytes. Finally, this Minireview offers insight into potential future directions in the design of innovative vanadium‐based electrode materials. Vanadium‐based compounds are widely implemented as cathodes for aqueous zinc‐ion batteries (ZIBs) because of their low cost and high theoretical capacity. 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source Wiley Online Library Journals Frontfile Complete
subjects Additives
aqueous ZIBs
Batteries
Cathodes
Electrochemical analysis
Electrochemistry
Electrode materials
Electrolytes
Energy storage
energy storage mechanisms
Low cost
Metal ions
Optimization
Reviews
Storage batteries
Storage systems
Vanadium
Vanadium compounds
vanadium-based compounds
Zinc
title Design Strategies for Vanadium‐based Aqueous Zinc‐Ion Batteries
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