Adsorption capacity of heavy metal ions using sultone-modified magnetic activated carbon as a bio-adsorbent
A novel magnetic bio-adsorbent has been prepared by the loading of Fe3O4 NPs and immobilization of 1,4-butane sultone on the surface of activated carbon. The activated carbon was synthesized from pistachio shell as a carbon material of biogenic, bio-resources and its use is cost effective. Structure...
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description | A novel magnetic bio-adsorbent has been prepared by the loading of Fe3O4 NPs and immobilization of 1,4-butane sultone on the surface of activated carbon. The activated carbon was synthesized from pistachio shell as a carbon material of biogenic, bio-resources and its use is cost effective. Structure, morphology and magnetic property of the prepared adsorbent were studied by transmission electron microscopy (TEM), vibrating sample magnetometer (VSM), Fourier transform infrared spectroscopy (FT-IR), and thermal gravimetric analysis (TGA). The capacity of the adsorbent for removing heavy metals ions Pb(II), As(III) and Cd(II) was studied using Langmuir adsorption isotherm under ultrasound-assisted condition. The maximum adsorption capacities of Pb(II), As(III) and Cd(II) were found to be 147.05, 151.51 and 119.04 mg g−1, respectively. In addition to high adsorption capacity, this adsorbent shows advantages such as green synthesis, low cast, recyclability, and easy separation. So this nanocomposite can be a suitable absorbent for removal of heavy metal ions from aqueous solutions. Meanwhile, the use of ultrasound radiation is an effective and rapid uptake technology for separating of heavy metal ions from aqueous solutions.
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•A novel magnetic bio-adsorbent for removal of heavy metal ions from aqueous•Synthesis of Fe3O4 NPs@AC@C4H8SO3H with high adsorption capacity•Easy separation of the bio-adsorbent from the reaction medium by an external magnet |
doi_str_mv | 10.1016/j.msec.2019.03.081 |
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•A novel magnetic bio-adsorbent for removal of heavy metal ions from aqueous•Synthesis of Fe3O4 NPs@AC@C4H8SO3H with high adsorption capacity•Easy separation of the bio-adsorbent from the reaction medium by an external magnet</description><identifier>ISSN: 0928-4931</identifier><identifier>EISSN: 1873-0191</identifier><identifier>DOI: 10.1016/j.msec.2019.03.081</identifier><identifier>PMID: 31029336</identifier><language>eng</language><publisher>Netherlands: Elsevier B.V</publisher><subject>Activated carbon ; Adsorbents ; Adsorption ; Adsorption capacity ; Aqueous solutions ; Butane ; Cadmium ; Carbon ; Charcoal - chemistry ; Fe3O4 NPs@AC@SO3H ; Fourier transforms ; Gravimetric analysis ; Heavy metals ; Hydrogen-Ion Concentration ; Immobilization ; Infrared analysis ; Infrared spectroscopy ; Ions ; Iron oxides ; Kinetics ; Lead ; Magnetic properties ; Magnetics ; Materials science ; Metal ions ; Metals, Heavy - analysis ; Morphology ; Nanocomposites ; Nanoparticles - chemistry ; Nanoparticles - ultrastructure ; Naphthalenesulfonates - chemistry ; Particle Size ; Radiation ; Recyclability ; Spectroscopy, Fourier Transform Infrared ; Thermal analysis ; Thermodynamics ; Thermogravimetry ; Time Factors ; Transmission electron microscopy ; Ultrasonic imaging ; Ultrasound ; X-Ray Diffraction</subject><ispartof>Materials Science & Engineering C, 2019-08, Vol.101, p.42-52</ispartof><rights>2019 Elsevier B.V.</rights><rights>Copyright © 2019 Elsevier B.V. All rights reserved.</rights><rights>Copyright Elsevier BV Aug 2019</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c421t-4e7a45a2cb56ac73de57250c1815f72d522169f6cbc89effe071342a8334330b3</citedby><cites>FETCH-LOGICAL-c421t-4e7a45a2cb56ac73de57250c1815f72d522169f6cbc89effe071342a8334330b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.msec.2019.03.081$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31029336$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Nejadshafiee, Vajihe</creatorcontrib><creatorcontrib>Islami, Mohammad Reza</creatorcontrib><title>Adsorption capacity of heavy metal ions using sultone-modified magnetic activated carbon as a bio-adsorbent</title><title>Materials Science & Engineering C</title><addtitle>Mater Sci Eng C Mater Biol Appl</addtitle><description>A novel magnetic bio-adsorbent has been prepared by the loading of Fe3O4 NPs and immobilization of 1,4-butane sultone on the surface of activated carbon. The activated carbon was synthesized from pistachio shell as a carbon material of biogenic, bio-resources and its use is cost effective. Structure, morphology and magnetic property of the prepared adsorbent were studied by transmission electron microscopy (TEM), vibrating sample magnetometer (VSM), Fourier transform infrared spectroscopy (FT-IR), and thermal gravimetric analysis (TGA). The capacity of the adsorbent for removing heavy metals ions Pb(II), As(III) and Cd(II) was studied using Langmuir adsorption isotherm under ultrasound-assisted condition. The maximum adsorption capacities of Pb(II), As(III) and Cd(II) were found to be 147.05, 151.51 and 119.04 mg g−1, respectively. In addition to high adsorption capacity, this adsorbent shows advantages such as green synthesis, low cast, recyclability, and easy separation. So this nanocomposite can be a suitable absorbent for removal of heavy metal ions from aqueous solutions. Meanwhile, the use of ultrasound radiation is an effective and rapid uptake technology for separating of heavy metal ions from aqueous solutions.
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•A novel magnetic bio-adsorbent for removal of heavy metal ions from aqueous•Synthesis of Fe3O4 NPs@AC@C4H8SO3H with high adsorption capacity•Easy separation of the bio-adsorbent from the reaction medium by an external magnet</description><subject>Activated carbon</subject><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Adsorption capacity</subject><subject>Aqueous solutions</subject><subject>Butane</subject><subject>Cadmium</subject><subject>Carbon</subject><subject>Charcoal - chemistry</subject><subject>Fe3O4 NPs@AC@SO3H</subject><subject>Fourier transforms</subject><subject>Gravimetric analysis</subject><subject>Heavy metals</subject><subject>Hydrogen-Ion Concentration</subject><subject>Immobilization</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Ions</subject><subject>Iron oxides</subject><subject>Kinetics</subject><subject>Lead</subject><subject>Magnetic properties</subject><subject>Magnetics</subject><subject>Materials science</subject><subject>Metal ions</subject><subject>Metals, Heavy - analysis</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Nanoparticles - chemistry</subject><subject>Nanoparticles - ultrastructure</subject><subject>Naphthalenesulfonates - chemistry</subject><subject>Particle Size</subject><subject>Radiation</subject><subject>Recyclability</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Thermal analysis</subject><subject>Thermodynamics</subject><subject>Thermogravimetry</subject><subject>Time Factors</subject><subject>Transmission electron microscopy</subject><subject>Ultrasonic imaging</subject><subject>Ultrasound</subject><subject>X-Ray Diffraction</subject><issn>0928-4931</issn><issn>1873-0191</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kU9v1DAQxS0EokvhC3BAlrhwSWp7kjiRuFRV-SNV6qU9WxNnUrwk8WI7K-23x9EWDhw4jTTze29G8xh7L0UphWyu9uUcyZZKyK4UUIpWvmA72Woocke-ZDvRqbaoOpAX7E2MeyGaFrR6zS5ACtUBNDv283qIPhyS8wu3eEDr0on7kf8gPJ74TAknnmeRr9EtTzyuU_ILFbMf3Oho4DM-LZSc5WiTO2LKLYuhz24YOfLe-QK3DT0t6S17NeIU6d1zvWSPX24fbr4Vd_dfv99c3xW2UjIVFWmsalS2rxu0GgaqtaqFla2sR62GWinZdGNje9t2NI4ktIRKYQtQAYgeLtmns-8h-F8rxWRmFy1NEy7k12g2vdbQCcjox3_QvV_Dkq_LVFU1tcglU-pM2eBjDDSaQ3AzhpORwmxRmL3ZojBbFEaAyVFk0Ydn67Wfafgr-fP7DHw-A5R_cXQUTLSOFkuDC2STGbz7n_9vjJaaRQ</recordid><startdate>20190801</startdate><enddate>20190801</enddate><creator>Nejadshafiee, Vajihe</creator><creator>Islami, Mohammad Reza</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>20190801</creationdate><title>Adsorption capacity of heavy metal ions using sultone-modified magnetic activated carbon as a bio-adsorbent</title><author>Nejadshafiee, Vajihe ; Islami, Mohammad Reza</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c421t-4e7a45a2cb56ac73de57250c1815f72d522169f6cbc89effe071342a8334330b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Activated carbon</topic><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Adsorption capacity</topic><topic>Aqueous solutions</topic><topic>Butane</topic><topic>Cadmium</topic><topic>Carbon</topic><topic>Charcoal - chemistry</topic><topic>Fe3O4 NPs@AC@SO3H</topic><topic>Fourier transforms</topic><topic>Gravimetric analysis</topic><topic>Heavy metals</topic><topic>Hydrogen-Ion Concentration</topic><topic>Immobilization</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Ions</topic><topic>Iron oxides</topic><topic>Kinetics</topic><topic>Lead</topic><topic>Magnetic properties</topic><topic>Magnetics</topic><topic>Materials science</topic><topic>Metal ions</topic><topic>Metals, Heavy - analysis</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Nanoparticles - chemistry</topic><topic>Nanoparticles - ultrastructure</topic><topic>Naphthalenesulfonates - chemistry</topic><topic>Particle Size</topic><topic>Radiation</topic><topic>Recyclability</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Thermal analysis</topic><topic>Thermodynamics</topic><topic>Thermogravimetry</topic><topic>Time Factors</topic><topic>Transmission electron microscopy</topic><topic>Ultrasonic imaging</topic><topic>Ultrasound</topic><topic>X-Ray Diffraction</topic><toplevel>online_resources</toplevel><creatorcontrib>Nejadshafiee, Vajihe</creatorcontrib><creatorcontrib>Islami, Mohammad Reza</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Materials Science & Engineering C</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nejadshafiee, Vajihe</au><au>Islami, Mohammad Reza</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adsorption capacity of heavy metal ions using sultone-modified magnetic activated carbon as a bio-adsorbent</atitle><jtitle>Materials Science & Engineering C</jtitle><addtitle>Mater Sci Eng C Mater Biol Appl</addtitle><date>2019-08-01</date><risdate>2019</risdate><volume>101</volume><spage>42</spage><epage>52</epage><pages>42-52</pages><issn>0928-4931</issn><eissn>1873-0191</eissn><abstract>A novel magnetic bio-adsorbent has been prepared by the loading of Fe3O4 NPs and immobilization of 1,4-butane sultone on the surface of activated carbon. The activated carbon was synthesized from pistachio shell as a carbon material of biogenic, bio-resources and its use is cost effective. Structure, morphology and magnetic property of the prepared adsorbent were studied by transmission electron microscopy (TEM), vibrating sample magnetometer (VSM), Fourier transform infrared spectroscopy (FT-IR), and thermal gravimetric analysis (TGA). The capacity of the adsorbent for removing heavy metals ions Pb(II), As(III) and Cd(II) was studied using Langmuir adsorption isotherm under ultrasound-assisted condition. The maximum adsorption capacities of Pb(II), As(III) and Cd(II) were found to be 147.05, 151.51 and 119.04 mg g−1, respectively. In addition to high adsorption capacity, this adsorbent shows advantages such as green synthesis, low cast, recyclability, and easy separation. So this nanocomposite can be a suitable absorbent for removal of heavy metal ions from aqueous solutions. Meanwhile, the use of ultrasound radiation is an effective and rapid uptake technology for separating of heavy metal ions from aqueous solutions.
[Display omitted]
•A novel magnetic bio-adsorbent for removal of heavy metal ions from aqueous•Synthesis of Fe3O4 NPs@AC@C4H8SO3H with high adsorption capacity•Easy separation of the bio-adsorbent from the reaction medium by an external magnet</abstract><cop>Netherlands</cop><pub>Elsevier B.V</pub><pmid>31029336</pmid><doi>10.1016/j.msec.2019.03.081</doi><tpages>11</tpages></addata></record> |
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subjects | Activated carbon Adsorbents Adsorption Adsorption capacity Aqueous solutions Butane Cadmium Carbon Charcoal - chemistry Fe3O4 NPs@AC@SO3H Fourier transforms Gravimetric analysis Heavy metals Hydrogen-Ion Concentration Immobilization Infrared analysis Infrared spectroscopy Ions Iron oxides Kinetics Lead Magnetic properties Magnetics Materials science Metal ions Metals, Heavy - analysis Morphology Nanocomposites Nanoparticles - chemistry Nanoparticles - ultrastructure Naphthalenesulfonates - chemistry Particle Size Radiation Recyclability Spectroscopy, Fourier Transform Infrared Thermal analysis Thermodynamics Thermogravimetry Time Factors Transmission electron microscopy Ultrasonic imaging Ultrasound X-Ray Diffraction |
title | Adsorption capacity of heavy metal ions using sultone-modified magnetic activated carbon as a bio-adsorbent |
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