Cobalt- and Nickel-Containing Germanotungstates Based on Open Wells–Dawson Structure: Synthesis and Characterization of Tetrameric Anion

Cobalt- and Nickel-Containing Germanotungstates Based on Open Wells–Dawson Structure: Synthesis and Characterization of Tetrameric Anion

Two transition-metal-substituted compounds K10H10{[Co­(H2O)2]2[Co­(H2O)3]2(Ge4W36O130)}·32H2O (1Co) and K10H10{[Ni­(H2O)2]2[Ni­(H2O)3]2(Ge4W36O130)}·32H2O (2Ni), have been successfully synthesized, both of which consist of the S-shaped tetrameric structure {Ge4W36} constructed from trivacant Keggin-...

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Veröffentlicht in:Inorganic chemistry 2019-05, Vol.58 (9), p.6000-6007
Hauptverfasser: Dong, Kaili, Ma, Pengtao, Wu, Hechen, Wu, Yuke, Niu, Jingyang, Wang, Jingping
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container_end_page 6007
container_issue 9
container_start_page 6000
container_title Inorganic chemistry
container_volume 58
creator Dong, Kaili
Ma, Pengtao
Wu, Hechen
Wu, Yuke
Niu, Jingyang
Wang, Jingping
description Two transition-metal-substituted compounds K10H10{[Co­(H2O)2]2[Co­(H2O)3]2(Ge4W36O130)}·32H2O (1Co) and K10H10{[Ni­(H2O)2]2[Ni­(H2O)3]2(Ge4W36O130)}·32H2O (2Ni), have been successfully synthesized, both of which consist of the S-shaped tetrameric structure {Ge4W36} constructed from trivacant Keggin-type germanotungstate precursor K8Na2[A-α-GeW9O34]·25H2O. These compounds were characterized by single crystal X-ray diffraction crystallography, X-ray powder diffraction (XRD), Raman spectra, thermogravimetric analysis (TGA), electrochemistry, and IR spectra. In addition, the UV spectra and the electrospray-ionization mass spectra (ESI-MS) were employed to investigated the stable pH value range of 1Co and 2Ni in aqueous solution.
doi_str_mv 10.1021/acs.inorgchem.9b00315
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title Cobalt- and Nickel-Containing Germanotungstates Based on Open Wells–Dawson Structure: Synthesis and Characterization of Tetrameric Anion
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