Zirconium complexes supported by a ferrocene-based ligand as redox switches for hydroamination reactions

The synthesis of (thiolfan*)Zr(NEt2)2 (thiolfan* = 1,1'-bis(2,4-di-tert-butyl-6-thiophenoxy)ferrocene) and its catalytic activity for intramolecular hydroamination are reported. In situ oxidation and reduction of the metal complex results in reactivity towards different substrates. The reduced...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2019-05, Vol.55 (39), p.5587-5590
Hauptverfasser:	Shen, Yi, Shepard, Scott M, Reed, Christopher J, Diaconescu, Paula L
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalytic activity Chemical reactions Coordination compounds Oxidation Reduction (metal working) Substrates Switches Zirconium
Online-Zugang:	Volltext
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