Selective C–C bond formation from rhodium-catalyzed C–H activation reaction of 2-arylpyridines with 3-aryl-2H-azirines

A novel method for the synthesis of acylmethyl-substituted 2-arylpyridine derivatives using 3-aryl-2H-azirines was developed by exploring a prototype reaction using DFT-calculations and carrying out targeted experiments guided by the calculated mechanism. 2H-Azirine was initially hypothesized to rin...

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Veröffentlicht in:	Chemical science (Cambridge) 2019-03, Vol.10 (9), p.2678-2686
Hauptverfasser:	Baek, Yonghyeon, Kim, Jinwoo, Hyunseok Kim, Seung Jin Jung, Ho, Ryu, Kim, Suyeon, Jeong-Yu, Son, Um, Kyusik, Han, Sang Hoon, Hyung Jin Seo, Heo, Juyoung, Lee, Kooyeon, Mu-Hyun Baik, Phil Ho Lee
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Catalysis Coordination compounds Coupling Functional groups Imines Mathematical analysis Rhodium Substitutes Substrates Synthesis
Online-Zugang:	Volltext
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