Evaluating the impacts of amino acids in the second and outer coordination spheres of Rh-bis(diphosphine) complexes for CO2 hydrogenation

To explore the influence of a biologically inspired second and outer coordination sphere on Rh-bis(diphosphine) CO2 hydrogenation catalysts, a series of five complexes were prepared by varying the substituents on the pendant amine in the P(Et)2CH2NRCH2P(Et)2 ligands (PEtNRPEt), where R consists of m...

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Veröffentlicht in:	Faraday discussions 2019, Vol.215, p.123-140
Hauptverfasser:	Walsh, Aaron P, Laureanti, Joseph A, Katipamula, Sriram, Chambers, Geoffrey M, Priyadarshani, Nilusha, Lense, Sheri, Bays, J Timothy, Linehan, John C, Shaw, Wendy J
Format:	Artikel
Sprache:	eng
Schlagworte:	Amino acids Aspartic acid Carbon dioxide Catalysis Catalysts Catalytic activity Coordination Crystallography Esters Food processing industry Glycine Histidine Hydrogenation Leucine Phenylalanine Phenylalanine methyl ester Rhodium
Online-Zugang:	Volltext
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