A new route to tricyclane sesquiterpenoids: total synthesis of α-ekasantalic acid

A new route to tricyclane sesquiterpenoids: total synthesis of α-ekasantalic acid

Chemical manipulation of the cycloadduct of citraconic anhydride and cyclopentadiene enables a new synthetic route to tricyclane sesquiterpenoids. This methodology is applied to the first total synthesis of α-ekasantalic acid.

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Veröffentlicht in:Organic & biomolecular chemistry 2019-05, Vol.17 (18), p.4456-4459
Hauptverfasser: Lomba, L, Afarinkia, K, Vinader, V
Format: Artikel
Sprache:eng
Schlagworte:
Acids
Anhydrides
Cyclopentadiene
Organic chemistry
Sesquiterpenoids
Synthesis
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container_title Organic & biomolecular chemistry
container_volume 17
creator Lomba, L
Afarinkia, K
Vinader, V
description Chemical manipulation of the cycloadduct of citraconic anhydride and cyclopentadiene enables a new synthetic route to tricyclane sesquiterpenoids. This methodology is applied to the first total synthesis of α-ekasantalic acid.
doi_str_mv 10.1039/c9ob00630c
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Acids
Anhydrides
Cyclopentadiene
Organic chemistry
Sesquiterpenoids
Synthesis
title A new route to tricyclane sesquiterpenoids: total synthesis of α-ekasantalic acid
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