Lead-Mediated Highly Diastereoselective Allylation of Aldehydes with Cyclic Allylic Halides

Lead was found to efficiently mediate the allylation reactions of carbonyl compounds with cyclic allylic halides in the presence of stoichiometric amounts of lithium chloride and a catalytic amount of GaCl3 (20 mol %), leading to the desired homoallylic alcohols in modest to high yields with excelle...

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Veröffentlicht in:	Journal of organic chemistry 2019-05, Vol.84 (9), p.5348-5356
Hauptverfasser:	Cheng, Bu-Qing, Zhao, Shi-Wen, Song, Xuan-Di, Chu, Xue-Qiang, Rao, Weidong, Loh, Teck-Peng, Shen, Zhi-Liang
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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