Synthesis of a Perfluorinated Phenoxyphosphorane and Conversion to Its Hexacoordinate Anions

We report the synthesis and structural characterization of a neutral PV Lewis acid, P(OC6F5)5, and salts containing the six‐coordinate anions [P(OC6F5)5F]− and [P(OC6F5)6]−. The latter anion exhibits a rare example of F–πarene interactions in both the solid and the solution phase, which has been qua...

Ausführliche Beschreibung