Photochemical, Metal‐Free Sigmatropic Rearrangement Reactions of Sulfur Ylides

Sigmatropic rearrangement reactions constitute one of the most fundamental reactions of carbenes. While state‐of‐the‐art synthetic methods require the use of expensive precious metal catalysts, the application of visible light for the photolysis of α‐aryldiazoacetates is much less investigated and p...

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Veröffentlicht in:	Chemistry : a European journal 2019-05, Vol.25 (27), p.6703-6706
Hauptverfasser:	Yang, Zhen, Guo, Yujing, Koenigs, Rene M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbenes Catalysts Chemistry diazoalkanes metal-free reactions Metals Photochemicals photochemistry Photolysis rearrangements Substitution reactions Sulfide Sulfur Sulfur compounds
Online-Zugang:	Volltext
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