Layered Thiazolo[5,4‑d] Thiazole-Linked Conjugated Microporous Polymers with Heteroatom Adoption for Efficient Photocatalysis Application

Layered Thiazolo[5,4‑d] Thiazole-Linked Conjugated Microporous Polymers with Heteroatom Adoption for Efficient Photocatalysis Application

Conjugated microporous polymers (CMPs) with high surface areas, tunable building blocks, and fully conjugated structures have found important applications in optoelectronics. Here, we report a new series of CMPs with tunable band gaps by introducing thiazolo­[5,4-d] thiazole as the linkage. Because...

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Veröffentlicht in:ACS applied materials & interfaces 2019-05, Vol.11 (17), p.15861-15868
Hauptverfasser: Huang, Qi, Guo, Liping, Wang, Ning, Zhu, Xiang, Jin, Shangbin, Tan, Bien
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container_end_page 15868
container_issue 17
container_start_page 15861
container_title ACS applied materials & interfaces
container_volume 11
creator Huang, Qi
Guo, Liping
Wang, Ning
Zhu, Xiang
Jin, Shangbin
Tan, Bien
description Conjugated microporous polymers (CMPs) with high surface areas, tunable building blocks, and fully conjugated structures have found important applications in optoelectronics. Here, we report a new series of CMPs with tunable band gaps by introducing thiazolo­[5,4-d] thiazole as the linkage. Because they are synthetic polymers, the geometries and structures could be rationally designed. Their intrinsic wide visible-light absorption properties and layered architectures endow them with a promising photocatalytic performance. The role of geometries, surface areas, and morphologies of the CMPs in photocatalysis abilities is examined and discussed. The results indicate that geometries have a direct impact on the surface areas and morphologies of the CMPs and thus exert great influence on photocatalysis.
doi_str_mv 10.1021/acsami.8b21765
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title Layered Thiazolo[5,4‑d] Thiazole-Linked Conjugated Microporous Polymers with Heteroatom Adoption for Efficient Photocatalysis Application
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