Stable Iron Porphyrin Intramolecularly Coordinated by Alcoholate Anion: Synthesis and Evaluation of Axial Ligand Effect of Alcoholate on Spectroscopy and Catalytic Activity

We synthesized intramolecularly aliphatic alcoholate-coordinated iron porphyrins (1a, 1b) that retain their axial coordination in the presence of another ligand or oxidant. The electron-donative character of alcoholate was less than that of thiolate, and the coordination ability of a sixth ligand to...

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Veröffentlicht in:	Inorganic chemistry 2019-04, Vol.58 (7), p.4268-4274
Hauptverfasser:	Shirakawa, Yoshinori, Yano, Yuuki, Niwa, Yuki, Inabe, Kanako, Umezawa, Naoki, Kato, Nobuki, Hisamatsu, Yosuke, Higuchi, Tsunehiko
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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