A kinetic model and computer simulation for a pulsed DF-CO2 chemical transfer laser

The chemical and energy transfer reactions involved in the helium-diluted DF-CO2 chemical transfer laser system are discussed. Experimental and theoretical rate coefficient literature is reviewed and the most probable rates are selected for the kinetic model of the reaction system. Results of comput...

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Veröffentlicht in:IEEE journal of quantum electronics 1973-01, Vol.QE-9, p.94-113
Hauptverfasser: Kerber, R L, Cohen, N, Emanuel, G
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Emanuel, G
description The chemical and energy transfer reactions involved in the helium-diluted DF-CO2 chemical transfer laser system are discussed. Experimental and theoretical rate coefficient literature is reviewed and the most probable rates are selected for the kinetic model of the reaction system. Results of computer experiments show the relative importance of these reactions for pulsed laser simulation. Predicted laser performance is most sensitive to values of rate coefficients for DF-CO2 transfer, collisional deactivation of CO2(00 1) by DF, and collisional deactivation of DF(v) by D and F. A detailed investigation of the relationship of cavity and chemical mechanisms for two levels of initiation is presented.
doi_str_mv 10.1109/JQE.1973.1077336
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title A kinetic model and computer simulation for a pulsed DF-CO2 chemical transfer laser
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