Metal‐Catalyzed Sequential Formation of Distant Bonds in Organic Molecules: Palladium‐Catalyzed Hydrosilylation/Cyclization of 1,n‐Dienes by Chain Walking

Sequential formation of distant bonds in organic molecules was achieved for the palladium‐catalyzed hydrosilylation/cyclization of various 1,n‐dienes by chain walking of the metal catalyst. The reaction was applicable to various 1,n‐dienes, including a 1,13‐diene, to form a cyclopentane ring as well...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2019-04, Vol.58 (16), p.5261-5265
Hauptverfasser:	Kochi, Takuya, Ichinose, Kazuya, Shigekane, Masayuki, Hamasaki, Taro, Kakiuchi, Fumitoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	alkenes Catalysis Chains Chemical bonds Chemical synthesis cyclizations Cyclopentane Dienes Hydrosilylation isomerizations Metals Organic chemistry Palladium
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!