Rhodium‐Catalyzed Stitching Polymerization of 1,5‐Hexadiynes and Related Oligoalkynes

A new mode of polymerization, rhodium‐catalyzed stitching polymerization, has been developed for the synthesis of π‐conjugated polymers with bridged repeating units from nonconjugated 1,5‐hexadiynes containing both terminal and internal alkyne moieties as monomers. The polymerization proceeded smoot...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie International Edition 2019-04, Vol.58 (17), p.5734-5738
Hauptverfasser:	Ikeda, Sho, Shintani, Ryo
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Chemical synthesis diynes Monomers oligoalkynes Polymerization Polymers Rhodium rhodium catalysis Stitching π-conjugated polymers
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!