KLi(HC3N3O3)·2H2O: Solvent-drop Grinding Method toward the Hydro-isocyanurate Nonlinear Optical Crystal

KLi(HC3N3O3)·2H2O: Solvent-drop Grinding Method toward the Hydro-isocyanurate Nonlinear Optical Crystal

A novel mixed alkali hydro-isocyanurate, KLi­(HC3N3O3)·2H2O was first prepared in AOH-BOH-H3C3N3O3 (A/B = Li/Na/K/Rb/Cs) system via a solvent-drop grinding method. KLi­(HC3N3O3)·2H2O shows a large second harmonic generation response (5.3 × KH2PO4) with an ultraviolet cutoff edge of 237 nm. More impo...

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Veröffentlicht in:Journal of the American Chemical Society 2019-02, Vol.141 (8), p.3390-3394
Hauptverfasser: Lin, Donghong, Luo, Min, Lin, Chensheng, Xu, Feng, Ye, Ning
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container_title Journal of the American Chemical Society
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creator Lin, Donghong
Luo, Min
Lin, Chensheng
Xu, Feng
Ye, Ning
description A novel mixed alkali hydro-isocyanurate, KLi­(HC3N3O3)·2H2O was first prepared in AOH-BOH-H3C3N3O3 (A/B = Li/Na/K/Rb/Cs) system via a solvent-drop grinding method. KLi­(HC3N3O3)·2H2O shows a large second harmonic generation response (5.3 × KH2PO4) with an ultraviolet cutoff edge of 237 nm. More importantly, the bulk single crystal can be readily grown through water solution technique. Characterization of these crystals indicates that KLi­(HC3N3O3)·2H2O has a high laser damage threshold (LDT) (4.76 GW/cm2) and exhibits a large birefringence (Δn = 0.186@514 nm), which reduces Type I phase-matching to 246 nm.
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Characterization of these crystals indicates that KLi­(HC3N3O3)·2H2O has a high laser damage threshold (LDT) (4.76 GW/cm2) and exhibits a large birefringence (Δn = 0.186@514 nm), which reduces Type I phase-matching to 246 nm.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/jacs.8b13280</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Journal of the American Chemical Society, 2019-02, Vol.141 (8), p.3390-3394</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-2102-8294 ; 0000-0001-9062-8931 ; 0000-0002-3679-4047</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jacs.8b13280$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jacs.8b13280$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,27058,27906,27907,56720,56770</link.rule.ids></links><search><creatorcontrib>Lin, Donghong</creatorcontrib><creatorcontrib>Luo, Min</creatorcontrib><creatorcontrib>Lin, Chensheng</creatorcontrib><creatorcontrib>Xu, Feng</creatorcontrib><creatorcontrib>Ye, Ning</creatorcontrib><title>KLi(HC3N3O3)·2H2O: Solvent-drop Grinding Method toward the Hydro-isocyanurate Nonlinear Optical Crystal</title><title>Journal of the American Chemical Society</title><addtitle>J. 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Characterization of these crystals indicates that KLi­(HC3N3O3)·2H2O has a high laser damage threshold (LDT) (4.76 GW/cm2) and exhibits a large birefringence (Δn = 0.186@514 nm), which reduces Type I phase-matching to 246 nm.</abstract><pub>American Chemical Society</pub><doi>10.1021/jacs.8b13280</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-2102-8294</orcidid><orcidid>https://orcid.org/0000-0001-9062-8931</orcidid><orcidid>https://orcid.org/0000-0002-3679-4047</orcidid></addata></record>
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