Flexible vanadium-doped Ni2P nanosheet arrays grown on carbon cloth for an efficient hydrogen evolution reaction
Tuning the electronic structure, morphology, and structure of electrocatalysts is of great significance to achieve a highly active and stable hydrogen evolution reaction (HER). Herein, combining hydrothermal and low temperature phosphidation methods, V-doped Ni2P nanosheet arrays grown on carbon clo...
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Veröffentlicht in: | Nanoscale 2019-03, Vol.11 (10), p.4198-4203 |
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creator | Wen, Lulu Yu, Jie Xing, Changchang Liu, Dilong Lyu, Xianjun Cai, Weiping Li, Xinyang |
description | Tuning the electronic structure, morphology, and structure of electrocatalysts is of great significance to achieve a highly active and stable hydrogen evolution reaction (HER). Herein, combining hydrothermal and low temperature phosphidation methods, V-doped Ni2P nanosheet arrays grown on carbon cloth (V-Ni2P NSAs/CC) were successfully prepared for the HER. It is found that the prepared V-Ni2P NSAs/CC exhibits preeminent performance for the HER. Specifically, it only requires an overpotential of 85 mV to achieve a current density of 10 mA cm−2 in 1.0 M KOH solution. Moreover, the V-Ni2P NSAs/CC shows superior electrochemical stability, maintaining its HER performance up to 3000 cyclic voltammetry cycles. This work affords a guiding strategy for the synthesis of a high-performance and stable electrocatalyst for the HER. |
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Herein, combining hydrothermal and low temperature phosphidation methods, V-doped Ni2P nanosheet arrays grown on carbon cloth (V-Ni2P NSAs/CC) were successfully prepared for the HER. It is found that the prepared V-Ni2P NSAs/CC exhibits preeminent performance for the HER. Specifically, it only requires an overpotential of 85 mV to achieve a current density of 10 mA cm−2 in 1.0 M KOH solution. Moreover, the V-Ni2P NSAs/CC shows superior electrochemical stability, maintaining its HER performance up to 3000 cyclic voltammetry cycles. This work affords a guiding strategy for the synthesis of a high-performance and stable electrocatalyst for the HER.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/c8nr10167a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Carbon ; Cloth ; Electrocatalysts ; Electronic structure ; Hydrogen evolution reactions ; Morphology ; Nanosheets ; Vanadium</subject><ispartof>Nanoscale, 2019-03, Vol.11 (10), p.4198-4203</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Wen, Lulu</creatorcontrib><creatorcontrib>Yu, Jie</creatorcontrib><creatorcontrib>Xing, Changchang</creatorcontrib><creatorcontrib>Liu, Dilong</creatorcontrib><creatorcontrib>Lyu, Xianjun</creatorcontrib><creatorcontrib>Cai, Weiping</creatorcontrib><creatorcontrib>Li, Xinyang</creatorcontrib><title>Flexible vanadium-doped Ni2P nanosheet arrays grown on carbon cloth for an efficient hydrogen evolution reaction</title><title>Nanoscale</title><description>Tuning the electronic structure, morphology, and structure of electrocatalysts is of great significance to achieve a highly active and stable hydrogen evolution reaction (HER). Herein, combining hydrothermal and low temperature phosphidation methods, V-doped Ni2P nanosheet arrays grown on carbon cloth (V-Ni2P NSAs/CC) were successfully prepared for the HER. It is found that the prepared V-Ni2P NSAs/CC exhibits preeminent performance for the HER. Specifically, it only requires an overpotential of 85 mV to achieve a current density of 10 mA cm−2 in 1.0 M KOH solution. Moreover, the V-Ni2P NSAs/CC shows superior electrochemical stability, maintaining its HER performance up to 3000 cyclic voltammetry cycles. This work affords a guiding strategy for the synthesis of a high-performance and stable electrocatalyst for the HER.</description><subject>Carbon</subject><subject>Cloth</subject><subject>Electrocatalysts</subject><subject>Electronic structure</subject><subject>Hydrogen evolution reactions</subject><subject>Morphology</subject><subject>Nanosheets</subject><subject>Vanadium</subject><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpdjz9PwzAUxC0EEqWw8AkssbAE_K-2M6KKAlIFDDBXtvPcpkrtYCeFfnsSgRiY7u7pp6c7hC4puaGEl7dOh0QJlcocoQkjghScK3b856U4RWc5bwmRJZd8gtpFA1-1bQDvTTBV3e-KKrZQ4eeaveJgQswbgA6blMwh43WKnwHHgJ1JdpQmdhvsY8ImYPC-djWEDm8OVYprGE772PRdPZAJjBvNOTrxpslw8atT9L64f5s_FsuXh6f53bJoqZBdAc5bQ7yfcWIJKZ02SoIWkqlhnfRC-TGDtFCBYJYZVVpKhGIMKDir-BRd__xtU_zoIXerXZ0dNI0JEPu8YlRLKvhsJgf06h-6jX0KQ7uR0pJoLSj_BryGaug</recordid><startdate>20190314</startdate><enddate>20190314</enddate><creator>Wen, Lulu</creator><creator>Yu, Jie</creator><creator>Xing, Changchang</creator><creator>Liu, Dilong</creator><creator>Lyu, Xianjun</creator><creator>Cai, Weiping</creator><creator>Li, Xinyang</creator><general>Royal Society of Chemistry</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope></search><sort><creationdate>20190314</creationdate><title>Flexible vanadium-doped Ni2P nanosheet arrays grown on carbon cloth for an efficient hydrogen evolution reaction</title><author>Wen, Lulu ; Yu, Jie ; Xing, Changchang ; Liu, Dilong ; Lyu, Xianjun ; Cai, Weiping ; Li, Xinyang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p146t-ecfba0ff530b009c8a76e846270166f47f76e8e6bede42b2a79b104722e1ecb73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Carbon</topic><topic>Cloth</topic><topic>Electrocatalysts</topic><topic>Electronic structure</topic><topic>Hydrogen evolution reactions</topic><topic>Morphology</topic><topic>Nanosheets</topic><topic>Vanadium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wen, Lulu</creatorcontrib><creatorcontrib>Yu, Jie</creatorcontrib><creatorcontrib>Xing, Changchang</creatorcontrib><creatorcontrib>Liu, Dilong</creatorcontrib><creatorcontrib>Lyu, Xianjun</creatorcontrib><creatorcontrib>Cai, Weiping</creatorcontrib><creatorcontrib>Li, Xinyang</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wen, Lulu</au><au>Yu, Jie</au><au>Xing, Changchang</au><au>Liu, Dilong</au><au>Lyu, Xianjun</au><au>Cai, Weiping</au><au>Li, Xinyang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Flexible vanadium-doped Ni2P nanosheet arrays grown on carbon cloth for an efficient hydrogen evolution reaction</atitle><jtitle>Nanoscale</jtitle><date>2019-03-14</date><risdate>2019</risdate><volume>11</volume><issue>10</issue><spage>4198</spage><epage>4203</epage><pages>4198-4203</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>Tuning the electronic structure, morphology, and structure of electrocatalysts is of great significance to achieve a highly active and stable hydrogen evolution reaction (HER). Herein, combining hydrothermal and low temperature phosphidation methods, V-doped Ni2P nanosheet arrays grown on carbon cloth (V-Ni2P NSAs/CC) were successfully prepared for the HER. It is found that the prepared V-Ni2P NSAs/CC exhibits preeminent performance for the HER. Specifically, it only requires an overpotential of 85 mV to achieve a current density of 10 mA cm−2 in 1.0 M KOH solution. Moreover, the V-Ni2P NSAs/CC shows superior electrochemical stability, maintaining its HER performance up to 3000 cyclic voltammetry cycles. This work affords a guiding strategy for the synthesis of a high-performance and stable electrocatalyst for the HER.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c8nr10167a</doi><tpages>6</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals 2008- |
subjects | Carbon Cloth Electrocatalysts Electronic structure Hydrogen evolution reactions Morphology Nanosheets Vanadium |
title | Flexible vanadium-doped Ni2P nanosheet arrays grown on carbon cloth for an efficient hydrogen evolution reaction |
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