Flexible vanadium-doped Ni2P nanosheet arrays grown on carbon cloth for an efficient hydrogen evolution reaction

Tuning the electronic structure, morphology, and structure of electrocatalysts is of great significance to achieve a highly active and stable hydrogen evolution reaction (HER). Herein, combining hydrothermal and low temperature phosphidation methods, V-doped Ni2P nanosheet arrays grown on carbon clo...

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Veröffentlicht in:Nanoscale 2019-03, Vol.11 (10), p.4198-4203
Hauptverfasser: Wen, Lulu, Yu, Jie, Xing, Changchang, Liu, Dilong, Lyu, Xianjun, Cai, Weiping, Li, Xinyang
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container_end_page 4203
container_issue 10
container_start_page 4198
container_title Nanoscale
container_volume 11
creator Wen, Lulu
Yu, Jie
Xing, Changchang
Liu, Dilong
Lyu, Xianjun
Cai, Weiping
Li, Xinyang
description Tuning the electronic structure, morphology, and structure of electrocatalysts is of great significance to achieve a highly active and stable hydrogen evolution reaction (HER). Herein, combining hydrothermal and low temperature phosphidation methods, V-doped Ni2P nanosheet arrays grown on carbon cloth (V-Ni2P NSAs/CC) were successfully prepared for the HER. It is found that the prepared V-Ni2P NSAs/CC exhibits preeminent performance for the HER. Specifically, it only requires an overpotential of 85 mV to achieve a current density of 10 mA cm−2 in 1.0 M KOH solution. Moreover, the V-Ni2P NSAs/CC shows superior electrochemical stability, maintaining its HER performance up to 3000 cyclic voltammetry cycles. This work affords a guiding strategy for the synthesis of a high-performance and stable electrocatalyst for the HER.
doi_str_mv 10.1039/c8nr10167a
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source Royal Society Of Chemistry Journals 2008-
subjects Carbon
Cloth
Electrocatalysts
Electronic structure
Hydrogen evolution reactions
Morphology
Nanosheets
Vanadium
title Flexible vanadium-doped Ni2P nanosheet arrays grown on carbon cloth for an efficient hydrogen evolution reaction
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