Metal-Free Catalytic Synthesis of Thiocarbamates Using Sodium Sulfinates as the Sulfur Source

Metal-Free Catalytic Synthesis of Thiocarbamates Using Sodium Sulfinates as the Sulfur Source

A novel molecular iodine-catalyzed protocol for the construction of thiocarbamates from readily available sodium sulfinates, isocyanides, and water has been described. The present methodology offers a facile and practical route to a variety of thiocarbamates in moderate to good yields with favorable...

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Veröffentlicht in:Journal of organic chemistry 2019-03, Vol.84 (5), p.2976-2983
Hauptverfasser: Bao, Pengli, Wang, Leilei, Yue, Huilan, Shao, Yun, Wen, Jiangwei, Yang, Daoshan, Zhao, Xiaohui, Wang, Hua, Wei, Wei
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container_end_page 2983
container_issue 5
container_start_page 2976
container_title Journal of organic chemistry
container_volume 84
creator Bao, Pengli
Wang, Leilei
Yue, Huilan
Shao, Yun
Wen, Jiangwei
Yang, Daoshan
Zhao, Xiaohui
Wang, Hua
Wei, Wei
description A novel molecular iodine-catalyzed protocol for the construction of thiocarbamates from readily available sodium sulfinates, isocyanides, and water has been described. The present methodology offers a facile and practical route to a variety of thiocarbamates in moderate to good yields with favorable functional group tolerance by use odorless sodium sulfinates as the sulfur source. The mechanistic studies suggest the present transformation involves a radical process.
doi_str_mv 10.1021/acs.joc.8b02844
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title Metal-Free Catalytic Synthesis of Thiocarbamates Using Sodium Sulfinates as the Sulfur Source
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