Colloidal tectonics for tandem synergistic Pickering interfacial catalysis: oxidative cleavage of cyclohexene oxide into adipic acid
Supramolecular preorganization and interfacial recognition can provide useful architectures for colloidal building. To this aim, a novel approach, based on colloidal tectonics involving two surface-active particles containing both recognition and catalytic sites, has been developed for controlling t...
Gespeichert in:
| Veröffentlicht in: | Chemical science (Cambridge) 2019-01, Vol.1 (2), p.51-57 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 57 |
|---|---|
| container_issue | 2 |
| container_start_page | 51 |
| container_title | Chemical science (Cambridge) |
| container_volume | 1 |
| creator | Yang, Bingyu Leclercq, Loïc Schmitt, Véronique Pera-Titus, Marc Nardello-Rataj, Véronique |
| description | Supramolecular preorganization and interfacial recognition can provide useful architectures for colloidal building. To this aim, a novel approach, based on colloidal tectonics involving two surface-active particles containing both recognition and catalytic sites, has been developed for controlling the formation and the properties of Pickering emulsions. This was illustrated by the combination of dodecyltrimethylammonium phosphotungstate nanoparticles, [C
12
]
3
[PW
12
O
40
], and silica particles functionalized with alkyl and sulfonic acid groups, [C
n
/SO
3
H]@SiO
2
. The interfacial self-assembly occurs by the penetration of the alkyl chains of [C
n
/SO
3
H]@SiO
2
into the [C
12
]
3
[PW
12
O
40
] supramolecular porous structure constituted of polar and apolar regions. The emulsions were used as a non-nitric acid route for adipic acid synthesis from the one-pot oxidative cleavage of cyclohexene oxide with aqueous H
2
O
2
. The catalytic performance was significantly boosted due to the synergistic interactions between the particles.
Supramolecular preorganization can provide useful architectures for colloidal building and catalytic applications. |
| doi_str_mv | 10.1039/c8sc03345e |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_proquest_miscellaneous_2179538794</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2162809465</sourcerecordid><originalsourceid>FETCH-LOGICAL-c462t-7ba5ae901eb9643e2f154779ff70bc9d17759c6260a4a7512ac473140b6a2fcf3</originalsourceid><addsrcrecordid>eNpdkk1vEzEQhi0EolXohTvIEhdACvhr7ZgDUrVqKVIkkIDzyjs7m7g462BvoubOD6_TlAD1xZbnmXfsmZeQ55y940za9zDLwKRUFT4ip4IpPtWVtI-PZ8FOyFnO16wsKXklzFNyIpnhUitzSn7XMYToOxfoiDDGwUOmfUx0dEOHK5p3A6aFz6MH-tXDT0x-WFA_jJh6B76kgRtd2GWfP9B4U4RGv0UKAd3WLZDGnsIOQlziDQ54R-A-PVLX-XURLSLdM_KkdyHj2f0-IT8uL77XV9P5l0-f6_P5FJQW49S0rnJoGcfWaiVR9LxSxti-N6wF23FjKgtaaOaUMxUXDpSRXLFWO9FDLyfk40F3vWlX2AEOY3KhWSe_cmnXROeb_yODXzaLuG10abCyugi8OQgsH6Rdnc-b_R0T3Ahu5ZYX9vV9sRR_bTCPzcpnwBDcgHGTm0LaSs6MVQV99QC9jps0lFYUSosZs6oMdULeHihIMeeE_fEFnDV7LzT17Ft954WLAr_896tH9M_kC_DiAKQMx-hfM8lblLK6sA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2162809465</pqid></control><display><type>article</type><title>Colloidal tectonics for tandem synergistic Pickering interfacial catalysis: oxidative cleavage of cyclohexene oxide into adipic acid</title><source>DOAJ Directory of Open Access Journals</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central</source><source>PubMed Central Open Access</source><creator>Yang, Bingyu ; Leclercq, Loïc ; Schmitt, Véronique ; Pera-Titus, Marc ; Nardello-Rataj, Véronique</creator><creatorcontrib>Yang, Bingyu ; Leclercq, Loïc ; Schmitt, Véronique ; Pera-Titus, Marc ; Nardello-Rataj, Véronique</creatorcontrib><description>Supramolecular preorganization and interfacial recognition can provide useful architectures for colloidal building. To this aim, a novel approach, based on colloidal tectonics involving two surface-active particles containing both recognition and catalytic sites, has been developed for controlling the formation and the properties of Pickering emulsions. This was illustrated by the combination of dodecyltrimethylammonium phosphotungstate nanoparticles, [C
12
]
3
[PW
12
O
40
], and silica particles functionalized with alkyl and sulfonic acid groups, [C
n
/SO
3
H]@SiO
2
. The interfacial self-assembly occurs by the penetration of the alkyl chains of [C
n
/SO
3
H]@SiO
2
into the [C
12
]
3
[PW
12
O
40
] supramolecular porous structure constituted of polar and apolar regions. The emulsions were used as a non-nitric acid route for adipic acid synthesis from the one-pot oxidative cleavage of cyclohexene oxide with aqueous H
2
O
2
. The catalytic performance was significantly boosted due to the synergistic interactions between the particles.
Supramolecular preorganization can provide useful architectures for colloidal building and catalytic applications.</description><identifier>ISSN: 2041-6520</identifier><identifier>EISSN: 2041-6539</identifier><identifier>DOI: 10.1039/c8sc03345e</identifier><identifier>PMID: 30713647</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Acids ; Catalysis ; Chemistry ; Cleavage ; Colloids ; Condensed Matter ; Cyclohexene ; Emulsions ; Hydrogen peroxide ; Nanoparticles ; Nitric acid ; Physics ; Plate tectonics ; Recognition ; Self-assembly ; Silicon dioxide ; Sulfonic acid ; Tectonics</subject><ispartof>Chemical science (Cambridge), 2019-01, Vol.1 (2), p.51-57</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><rights>This journal is © The Royal Society of Chemistry 2019 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c462t-7ba5ae901eb9643e2f154779ff70bc9d17759c6260a4a7512ac473140b6a2fcf3</citedby><cites>FETCH-LOGICAL-c462t-7ba5ae901eb9643e2f154779ff70bc9d17759c6260a4a7512ac473140b6a2fcf3</cites><orcidid>0000-0001-7335-1424 ; 0000-0001-8065-997X ; 0000-0002-9206-3863 ; 0000-0002-9938-9911</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6334496/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6334496/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30713647$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-02172193$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Yang, Bingyu</creatorcontrib><creatorcontrib>Leclercq, Loïc</creatorcontrib><creatorcontrib>Schmitt, Véronique</creatorcontrib><creatorcontrib>Pera-Titus, Marc</creatorcontrib><creatorcontrib>Nardello-Rataj, Véronique</creatorcontrib><title>Colloidal tectonics for tandem synergistic Pickering interfacial catalysis: oxidative cleavage of cyclohexene oxide into adipic acid</title><title>Chemical science (Cambridge)</title><addtitle>Chem Sci</addtitle><description>Supramolecular preorganization and interfacial recognition can provide useful architectures for colloidal building. To this aim, a novel approach, based on colloidal tectonics involving two surface-active particles containing both recognition and catalytic sites, has been developed for controlling the formation and the properties of Pickering emulsions. This was illustrated by the combination of dodecyltrimethylammonium phosphotungstate nanoparticles, [C
12
]
3
[PW
12
O
40
], and silica particles functionalized with alkyl and sulfonic acid groups, [C
n
/SO
3
H]@SiO
2
. The interfacial self-assembly occurs by the penetration of the alkyl chains of [C
n
/SO
3
H]@SiO
2
into the [C
12
]
3
[PW
12
O
40
] supramolecular porous structure constituted of polar and apolar regions. The emulsions were used as a non-nitric acid route for adipic acid synthesis from the one-pot oxidative cleavage of cyclohexene oxide with aqueous H
2
O
2
. The catalytic performance was significantly boosted due to the synergistic interactions between the particles.
Supramolecular preorganization can provide useful architectures for colloidal building and catalytic applications.</description><subject>Acids</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Cleavage</subject><subject>Colloids</subject><subject>Condensed Matter</subject><subject>Cyclohexene</subject><subject>Emulsions</subject><subject>Hydrogen peroxide</subject><subject>Nanoparticles</subject><subject>Nitric acid</subject><subject>Physics</subject><subject>Plate tectonics</subject><subject>Recognition</subject><subject>Self-assembly</subject><subject>Silicon dioxide</subject><subject>Sulfonic acid</subject><subject>Tectonics</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpdkk1vEzEQhi0EolXohTvIEhdACvhr7ZgDUrVqKVIkkIDzyjs7m7g462BvoubOD6_TlAD1xZbnmXfsmZeQ55y940za9zDLwKRUFT4ip4IpPtWVtI-PZ8FOyFnO16wsKXklzFNyIpnhUitzSn7XMYToOxfoiDDGwUOmfUx0dEOHK5p3A6aFz6MH-tXDT0x-WFA_jJh6B76kgRtd2GWfP9B4U4RGv0UKAd3WLZDGnsIOQlziDQ54R-A-PVLX-XURLSLdM_KkdyHj2f0-IT8uL77XV9P5l0-f6_P5FJQW49S0rnJoGcfWaiVR9LxSxti-N6wF23FjKgtaaOaUMxUXDpSRXLFWO9FDLyfk40F3vWlX2AEOY3KhWSe_cmnXROeb_yODXzaLuG10abCyugi8OQgsH6Rdnc-b_R0T3Ahu5ZYX9vV9sRR_bTCPzcpnwBDcgHGTm0LaSs6MVQV99QC9jps0lFYUSosZs6oMdULeHihIMeeE_fEFnDV7LzT17Ft954WLAr_896tH9M_kC_DiAKQMx-hfM8lblLK6sA</recordid><startdate>20190114</startdate><enddate>20190114</enddate><creator>Yang, Bingyu</creator><creator>Leclercq, Loïc</creator><creator>Schmitt, Véronique</creator><creator>Pera-Titus, Marc</creator><creator>Nardello-Rataj, Véronique</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>1XC</scope><scope>VOOES</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-7335-1424</orcidid><orcidid>https://orcid.org/0000-0001-8065-997X</orcidid><orcidid>https://orcid.org/0000-0002-9206-3863</orcidid><orcidid>https://orcid.org/0000-0002-9938-9911</orcidid></search><sort><creationdate>20190114</creationdate><title>Colloidal tectonics for tandem synergistic Pickering interfacial catalysis: oxidative cleavage of cyclohexene oxide into adipic acid</title><author>Yang, Bingyu ; Leclercq, Loïc ; Schmitt, Véronique ; Pera-Titus, Marc ; Nardello-Rataj, Véronique</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c462t-7ba5ae901eb9643e2f154779ff70bc9d17759c6260a4a7512ac473140b6a2fcf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Acids</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Cleavage</topic><topic>Colloids</topic><topic>Condensed Matter</topic><topic>Cyclohexene</topic><topic>Emulsions</topic><topic>Hydrogen peroxide</topic><topic>Nanoparticles</topic><topic>Nitric acid</topic><topic>Physics</topic><topic>Plate tectonics</topic><topic>Recognition</topic><topic>Self-assembly</topic><topic>Silicon dioxide</topic><topic>Sulfonic acid</topic><topic>Tectonics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Bingyu</creatorcontrib><creatorcontrib>Leclercq, Loïc</creatorcontrib><creatorcontrib>Schmitt, Véronique</creatorcontrib><creatorcontrib>Pera-Titus, Marc</creatorcontrib><creatorcontrib>Nardello-Rataj, Véronique</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Bingyu</au><au>Leclercq, Loïc</au><au>Schmitt, Véronique</au><au>Pera-Titus, Marc</au><au>Nardello-Rataj, Véronique</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Colloidal tectonics for tandem synergistic Pickering interfacial catalysis: oxidative cleavage of cyclohexene oxide into adipic acid</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2019-01-14</date><risdate>2019</risdate><volume>1</volume><issue>2</issue><spage>51</spage><epage>57</epage><pages>51-57</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>Supramolecular preorganization and interfacial recognition can provide useful architectures for colloidal building. To this aim, a novel approach, based on colloidal tectonics involving two surface-active particles containing both recognition and catalytic sites, has been developed for controlling the formation and the properties of Pickering emulsions. This was illustrated by the combination of dodecyltrimethylammonium phosphotungstate nanoparticles, [C
12
]
3
[PW
12
O
40
], and silica particles functionalized with alkyl and sulfonic acid groups, [C
n
/SO
3
H]@SiO
2
. The interfacial self-assembly occurs by the penetration of the alkyl chains of [C
n
/SO
3
H]@SiO
2
into the [C
12
]
3
[PW
12
O
40
] supramolecular porous structure constituted of polar and apolar regions. The emulsions were used as a non-nitric acid route for adipic acid synthesis from the one-pot oxidative cleavage of cyclohexene oxide with aqueous H
2
O
2
. The catalytic performance was significantly boosted due to the synergistic interactions between the particles.
Supramolecular preorganization can provide useful architectures for colloidal building and catalytic applications.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30713647</pmid><doi>10.1039/c8sc03345e</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-7335-1424</orcidid><orcidid>https://orcid.org/0000-0001-8065-997X</orcidid><orcidid>https://orcid.org/0000-0002-9206-3863</orcidid><orcidid>https://orcid.org/0000-0002-9938-9911</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2041-6520 |
| ispartof | Chemical science (Cambridge), 2019-01, Vol.1 (2), p.51-57 |
| issn | 2041-6520 2041-6539 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2179538794 |
| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; PubMed Central Open Access |
| subjects | Acids Catalysis Chemistry Cleavage Colloids Condensed Matter Cyclohexene Emulsions Hydrogen peroxide Nanoparticles Nitric acid Physics Plate tectonics Recognition Self-assembly Silicon dioxide Sulfonic acid Tectonics |
| title | Colloidal tectonics for tandem synergistic Pickering interfacial catalysis: oxidative cleavage of cyclohexene oxide into adipic acid |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-28T11%3A35%3A05IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Colloidal%20tectonics%20for%20tandem%20synergistic%20Pickering%20interfacial%20catalysis:%20oxidative%20cleavage%20of%20cyclohexene%20oxide%20into%20adipic%20acid&rft.jtitle=Chemical%20science%20(Cambridge)&rft.au=Yang,%20Bingyu&rft.date=2019-01-14&rft.volume=1&rft.issue=2&rft.spage=51&rft.epage=57&rft.pages=51-57&rft.issn=2041-6520&rft.eissn=2041-6539&rft_id=info:doi/10.1039/c8sc03345e&rft_dat=%3Cproquest_rsc_p%3E2162809465%3C/proquest_rsc_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2162809465&rft_id=info:pmid/30713647&rfr_iscdi=true |