Analytical applications and physicochemical properties of ionic liquid-based hybrid materials: A review

Ionic liquids with their unique properties found so far numerous analytical applications. Among them ionic liquids immobilized on the surface or within the pores of a solid support were successfully utilized in extraction techniques dedicated to preconcentration of the analytes from food, environmen...

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Veröffentlicht in:Analytica chimica acta 2019-04, Vol.1054, p.1-16
Hauptverfasser: Yavir, Kateryna, Marcinkowski, Łukasz, Marcinkowska, Renata, Namieśnik, Jacek, Kloskowski, Adam
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container_title Analytica chimica acta
container_volume 1054
creator Yavir, Kateryna
Marcinkowski, Łukasz
Marcinkowska, Renata
Namieśnik, Jacek
Kloskowski, Adam
description Ionic liquids with their unique properties found so far numerous analytical applications. Among them ionic liquids immobilized on the surface or within the pores of a solid support were successfully utilized in extraction techniques dedicated to preconcentration of the analytes from food, environmental and biological samples. In this review we focus on comprehensive summarizing of available literature data on the examples of ionic liquid-based hybrid materials implementation in selected analytical extraction techniques, namely solid-phase extraction, solid-phase microextraction, hollow-fiber solid-phase microextraction, stir-bar sorptive extraction and biosensors. Additionally, this work is supported by concise discussion on strategies of ionic liquids immobilization in order to form hybrid materials (both chemical and physical) and the effects of confinement on structures along with ionic liquids physicochemical properties. This work allows for identifying the opportunities, challenges and shortcomings of this powerful and convenient, yet still not fully discovered analytical approach. [Display omitted] •Great potential of ILs immobilized on/in solid network as sorption materials has been presented.•Methods of ILs-based sorption hybrid materials synthesis have been presented.•Effects of confinement on structures and physicochemical properties of ILs have been summarized.•The application of ILs-based hybrid materials in extraction techniques have been reviewed.
doi_str_mv 10.1016/j.aca.2018.10.061
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subjects Analytical chemistry
Biological properties
Biological samples
Biosensors
Chemical Phenomena
Chemistry Techniques, Analytical - methods
Extraction
IL-based hybrid materials
Immobilization
Ionic liquids
Ionic Liquids - chemistry
Ions
Materials selection
Mathematical analysis
Organic chemistry
Physicochemical properties
Sample preparation techniques
Solid phase extraction
Solid phase methods
Solid Phase Microextraction
Solid phases
Solvents
Stir bar sorptive extraction
title Analytical applications and physicochemical properties of ionic liquid-based hybrid materials: A review
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