Reactions of 5‑Aminoisoxazoles with α‑Diazocarbonyl Compounds: Wolff Rearrangement vs N–H Insertion

A highly chemoselective reaction between 5-aminoisoxazoles and α-diazocarbonyl compounds has been described. Both Wolff rearrangement and N–H insertion products can be obtained selectively by the judicious choice of reaction conditions. In the case of the Wolff rearrangement reactions, the N-isoxazo...

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Veröffentlicht in:	Journal of organic chemistry 2019-03, Vol.84 (5), p.2676-2688
Hauptverfasser:	Ge, Yun, Sun, Wangbin, Chen, Yang, Huang, Yulin, Liu, Zhuang, Jiang, Yaojia, Loh, Teck-Peng
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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