Predictable Substituent Control of CoIII/II Redox Potential and Spin Crossover in Bis(dipyridylpyrrolide)cobalt Complexes

A family of five easily prepared tridentate monoanionic 2,5-dipyridyl-3-(R1)-4-(R2)-pyrrolide anions (dppR1,R2)−, varying in the nature of the R1 and R2 substituents [R1, R2 = CN, Ph; CO2Et, CO2Et; CO2Me, 4-Py; CO2Me, Me; Me, Me], has been used to generate the analogous family of neutral [CoII(dppR1...

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Veröffentlicht in:	Inorganic chemistry 2019-02, Vol.58 (3), p.2218-2228
Hauptverfasser:	McPherson, James N, Hogue, Ross W, Akogun, Folaranmi Sunday, Bondì, Luca, Luis, Ena T, Price, Jason R, Garden, Anna L, Brooker, Sally, Colbran, Stephen B
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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