Synthesis of MCM‐41‐Supported Metal Catalysts in Deep Eutectic Solvent for the Conversion of Carbohydrates into 5‐Hydroxymethylfurfural
A series of MCM‐41 supported metal catalysts (denoted M/D41) were prepared by using the deep eutectic solvent (DES)‐mediated ionothermal synthesis strategy. Al/D41 was found to have excellent performance in the conversion of carbohydrates into 5‐hydroxymethylfurfural (HMF). Furthermore, the producti...
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| Veröffentlicht in: | ChemSusChem 2019-03, Vol.12 (5), p.978-982 |
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| creator | Feng, Yunchao Yan, Guihua Wang, Ting Jia, Wenlong Zeng, Xianhai Sperry, Jonathan Sun, Yong Tang, Xing Lei, Tingzhou Lin, Lu |
| description | A series of MCM‐41 supported metal catalysts (denoted M/D41) were prepared by using the deep eutectic solvent (DES)‐mediated ionothermal synthesis strategy. Al/D41 was found to have excellent performance in the conversion of carbohydrates into 5‐hydroxymethylfurfural (HMF). Furthermore, the production of HMF from glucose could be performed at high concentrations in choline chloride aqueous solution (CAS; 32 wt %, relative to the reaction phase) and as a result, CAS is a more promising solvent than water and DES for HMF production.
MCM's grand: A series of MCM‐41 supported metal catalysts (denoted M/D41) were prepared by using the deep eutectic solvent (DES)‐mediated ionothermal synthesis strategy. Al/D41 showed excellent performance in the conversion of carbohydrates into 5‐hydroxymethylfurfural (HMF). Production of HMF from glucose could be performed at high concentrations in choline chloride aqueous solution. |
| doi_str_mv | 10.1002/cssc.201802792 |
| format | Article |
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MCM's grand: A series of MCM‐41 supported metal catalysts (denoted M/D41) were prepared by using the deep eutectic solvent (DES)‐mediated ionothermal synthesis strategy. Al/D41 showed excellent performance in the conversion of carbohydrates into 5‐hydroxymethylfurfural (HMF). Production of HMF from glucose could be performed at high concentrations in choline chloride aqueous solution.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.201802792</identifier><identifier>PMID: 30677241</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Aqueous solutions ; biomass ; Carbohydrates ; Catalysis ; Catalysts ; Chemical synthesis ; Choline ; Conversion ; deep eutectic solvents ; heterogeneous catalysis ; Hydroxymethylfurfural ; Solvents</subject><ispartof>ChemSusChem, 2019-03, Vol.12 (5), p.978-982</ispartof><rights>2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3732-66c29eb586d83e5c1ec5ccf97028dbc358e8708d7d10dacfffb5a6bde0a2750e3</citedby><cites>FETCH-LOGICAL-c3732-66c29eb586d83e5c1ec5ccf97028dbc358e8708d7d10dacfffb5a6bde0a2750e3</cites><orcidid>0000-0002-5441-3164</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcssc.201802792$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcssc.201802792$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27922,27923,45572,45573</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30677241$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Feng, Yunchao</creatorcontrib><creatorcontrib>Yan, Guihua</creatorcontrib><creatorcontrib>Wang, Ting</creatorcontrib><creatorcontrib>Jia, Wenlong</creatorcontrib><creatorcontrib>Zeng, Xianhai</creatorcontrib><creatorcontrib>Sperry, Jonathan</creatorcontrib><creatorcontrib>Sun, Yong</creatorcontrib><creatorcontrib>Tang, Xing</creatorcontrib><creatorcontrib>Lei, Tingzhou</creatorcontrib><creatorcontrib>Lin, Lu</creatorcontrib><title>Synthesis of MCM‐41‐Supported Metal Catalysts in Deep Eutectic Solvent for the Conversion of Carbohydrates into 5‐Hydroxymethylfurfural</title><title>ChemSusChem</title><addtitle>ChemSusChem</addtitle><description>A series of MCM‐41 supported metal catalysts (denoted M/D41) were prepared by using the deep eutectic solvent (DES)‐mediated ionothermal synthesis strategy. Al/D41 was found to have excellent performance in the conversion of carbohydrates into 5‐hydroxymethylfurfural (HMF). Furthermore, the production of HMF from glucose could be performed at high concentrations in choline chloride aqueous solution (CAS; 32 wt %, relative to the reaction phase) and as a result, CAS is a more promising solvent than water and DES for HMF production.
MCM's grand: A series of MCM‐41 supported metal catalysts (denoted M/D41) were prepared by using the deep eutectic solvent (DES)‐mediated ionothermal synthesis strategy. Al/D41 showed excellent performance in the conversion of carbohydrates into 5‐hydroxymethylfurfural (HMF). Production of HMF from glucose could be performed at high concentrations in choline chloride aqueous solution.</description><subject>Aqueous solutions</subject><subject>biomass</subject><subject>Carbohydrates</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical synthesis</subject><subject>Choline</subject><subject>Conversion</subject><subject>deep eutectic solvents</subject><subject>heterogeneous catalysis</subject><subject>Hydroxymethylfurfural</subject><subject>Solvents</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkU2LFDEQhhtxcdfVq0cJePEys_nofPRReldX2GEPreCtSScVppeeTpukV_vmHxD8jf4SM8zuCF6EoiqEpx4K3qJ4RfCaYEwvTIxmTTFRmMqKPinOiBLliovyy9Pjm5HT4nmMdxgLXAnxrDhlWEhJS3JW_GyWMW0h9hF5hzb15vePXyXJrZmnyYcEFm0g6QHVOvclpoj6EV0CTOhqTmBSb1Djh3sYE3I-oOxCtR_vIcTej3tnrUPnt4sNOsF-OXnEs_86__jvyw7SdhncHHLp4UVx4vQQ4eXDPC8-v7_6VF-vbm4_fKzf3awMk4yuhDC0go4rYRUDbggYboyrJKbKdoZxBUpiZaUl2GrjnOu4Fp0FrKnkGNh58fbgnYL_OkNM7a6PBoZBj-Dn2FIiq5JThnlG3_yD3vk5jPm6TCmlGC0pzdT6QJngYwzg2in0Ox2WluB2H1S7D6o9BpUXXj9o524H9og_JpOB6gB86wdY_qNr66ap_8r_AHxmpSQ</recordid><startdate>20190307</startdate><enddate>20190307</enddate><creator>Feng, Yunchao</creator><creator>Yan, Guihua</creator><creator>Wang, Ting</creator><creator>Jia, Wenlong</creator><creator>Zeng, Xianhai</creator><creator>Sperry, Jonathan</creator><creator>Sun, Yong</creator><creator>Tang, Xing</creator><creator>Lei, Tingzhou</creator><creator>Lin, Lu</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-5441-3164</orcidid></search><sort><creationdate>20190307</creationdate><title>Synthesis of MCM‐41‐Supported Metal Catalysts in Deep Eutectic Solvent for the Conversion of Carbohydrates into 5‐Hydroxymethylfurfural</title><author>Feng, Yunchao ; Yan, Guihua ; Wang, Ting ; Jia, Wenlong ; Zeng, Xianhai ; Sperry, Jonathan ; Sun, Yong ; Tang, Xing ; Lei, Tingzhou ; Lin, Lu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3732-66c29eb586d83e5c1ec5ccf97028dbc358e8708d7d10dacfffb5a6bde0a2750e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aqueous solutions</topic><topic>biomass</topic><topic>Carbohydrates</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical synthesis</topic><topic>Choline</topic><topic>Conversion</topic><topic>deep eutectic solvents</topic><topic>heterogeneous catalysis</topic><topic>Hydroxymethylfurfural</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Feng, Yunchao</creatorcontrib><creatorcontrib>Yan, Guihua</creatorcontrib><creatorcontrib>Wang, Ting</creatorcontrib><creatorcontrib>Jia, Wenlong</creatorcontrib><creatorcontrib>Zeng, Xianhai</creatorcontrib><creatorcontrib>Sperry, Jonathan</creatorcontrib><creatorcontrib>Sun, Yong</creatorcontrib><creatorcontrib>Tang, Xing</creatorcontrib><creatorcontrib>Lei, Tingzhou</creatorcontrib><creatorcontrib>Lin, Lu</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Feng, Yunchao</au><au>Yan, Guihua</au><au>Wang, Ting</au><au>Jia, Wenlong</au><au>Zeng, Xianhai</au><au>Sperry, Jonathan</au><au>Sun, Yong</au><au>Tang, Xing</au><au>Lei, Tingzhou</au><au>Lin, Lu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of MCM‐41‐Supported Metal Catalysts in Deep Eutectic Solvent for the Conversion of Carbohydrates into 5‐Hydroxymethylfurfural</atitle><jtitle>ChemSusChem</jtitle><addtitle>ChemSusChem</addtitle><date>2019-03-07</date><risdate>2019</risdate><volume>12</volume><issue>5</issue><spage>978</spage><epage>982</epage><pages>978-982</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>A series of MCM‐41 supported metal catalysts (denoted M/D41) were prepared by using the deep eutectic solvent (DES)‐mediated ionothermal synthesis strategy. Al/D41 was found to have excellent performance in the conversion of carbohydrates into 5‐hydroxymethylfurfural (HMF). Furthermore, the production of HMF from glucose could be performed at high concentrations in choline chloride aqueous solution (CAS; 32 wt %, relative to the reaction phase) and as a result, CAS is a more promising solvent than water and DES for HMF production.
MCM's grand: A series of MCM‐41 supported metal catalysts (denoted M/D41) were prepared by using the deep eutectic solvent (DES)‐mediated ionothermal synthesis strategy. Al/D41 showed excellent performance in the conversion of carbohydrates into 5‐hydroxymethylfurfural (HMF). Production of HMF from glucose could be performed at high concentrations in choline chloride aqueous solution.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>30677241</pmid><doi>10.1002/cssc.201802792</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-5441-3164</orcidid></addata></record> |
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| subjects | Aqueous solutions biomass Carbohydrates Catalysis Catalysts Chemical synthesis Choline Conversion deep eutectic solvents heterogeneous catalysis Hydroxymethylfurfural Solvents |
| title | Synthesis of MCM‐41‐Supported Metal Catalysts in Deep Eutectic Solvent for the Conversion of Carbohydrates into 5‐Hydroxymethylfurfural |
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