Photophysics of Cage/Guest Assemblies: Photoinduced Electron Transfer between a Coordination Cage Containing Osmium(II) Luminophores, and Electron-Deficient Bound Guests in the Central Cavity

A heterometallic octanuclear coordination cage [Os4Zn4(Lnap)12]­X16 (denoted Os•Zn; X = perchlorate or chloride) has been prepared (Lnap is a bis-bidentate bridging ligand containing two pyrazolyl–pyridine chelating units separated by a 1,5-naphthalenediyl spacer group). The {Os­(NN)3}2+ units locat...

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Veröffentlicht in:	Inorganic chemistry 2019-02, Vol.58 (4), p.2386-2396
Hauptverfasser:	Train, Jennifer S, Wragg, Ashley B, Auty, Alexander J, Metherell, Alexander J, Chekulaev, Dimitri, Taylor, Christopher G. P, Argent, Stephen P, Weinstein, Julia A, Ward, Michael D
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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