Understanding the Reactivity and Selectivity of Fluxional Chiral DMAP‐Catalyzed Kinetic Resolutions of Axially Chiral Biaryls

Fluxional chiral DMAP‐catalyzed kinetic resolutions of axially chiral biaryls were examined using density functional theory. Computational analyses lead to a revised understanding of this reaction in which the interplay of numerous non‐covalent interactions control the conformation and flexibility o...

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Veröffentlicht in:	Chemistry : a European journal 2019-03, Vol.25 (17), p.4452-4459
Hauptverfasser:	Maji, Rajat, Ugale, Heena, Wheeler, Steven E.
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts Chemistry chirality Computer applications Conformation density functional calculations Density functional theory kinetic resolutions non-covalent interactions Selectivity Stereoselectivity
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