Proton Affinities of N‑Heterocyclic Olefins and Their Implications for Organocatalyst Design
The proton affinity (PA) of a range of structurally different N-heterocycles with an exocyclic double bond (= N-heterocyclic olefins, NHOs) has been determined using DFT calculations on the BLYP/def2-TZVPP level. It was found that NHOs belong to the upper end of the superbasicity scale, covering PA...
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| Veröffentlicht in: | Journal of organic chemistry 2019-02, Vol.84 (4), p.2209-2218 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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