Sulfuryl Fluoride Mediated Conversion of Aldehydes to Nitriles

Aliphatic, aromatic, and heteroaromatic aldehydes were readily converted to corresponding nitriles in a one‐pot reaction sequence with hydroxylamine and sulfuryl fluoride. The reaction proceeds at room temperature, does not require metal catalysts and special precautions, and produces nitriles in ex...

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Veröffentlicht in:	Chemistry : a European journal 2019-02, Vol.25 (8), p.1906-1909
Hauptverfasser:	Gurjar, Jitendra, Bater, Jorick, Fokin, Valery V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Aliphatic compounds Alkynes bioorthogonal chemistry Catalysts Chemistry Cyanides Fluorides Functional groups Hydroxylamine main group elements Nitriles Organic solvents polyfunctional probes Selectivity Sulfuryl fluoride synthetic methods Temperature requirements
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