Isotope Labeling Reveals Fast Atomic and Molecular Exchange in Mechanochemical Milling Reactions
Using tandem in situ monitoring and isotope-labeled solids, we reveal that mechanochemical ball-milling overcomes inherently slow solid-state diffusion through continuous comminution and growth of milled particles. This process occurs with or without a net chemical reaction and also occurs between s...
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| Veröffentlicht in: | Journal of the American Chemical Society 2019-01, Vol.141 (3), p.1212-1216 |
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| container_end_page | 1216 |
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| container_issue | 3 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 141 |
| creator | Lukin, Stipe Tireli, Martina Stolar, Tomislav Barišić, Dajana Blanco, Maria Valeria di Michiel, Marco Užarević, Krunoslav Halasz, Ivan |
| description | Using tandem in situ monitoring and isotope-labeled solids, we reveal that mechanochemical ball-milling overcomes inherently slow solid-state diffusion through continuous comminution and growth of milled particles. This process occurs with or without a net chemical reaction and also occurs between solids and liquid additives that can be practically used for highly efficient deuterium labeling of solids. The presented findings reveal a fundamental aspect of milling reactions and also delineate a methodology that should be considered in the study of mechanochemical reaction mechanisms. |
| doi_str_mv | 10.1021/jacs.8b12149 |
| format | Article |
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| title | Isotope Labeling Reveals Fast Atomic and Molecular Exchange in Mechanochemical Milling Reactions |
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