An FeP@C nanoarray vertically grown on graphene nanosheets: an ultrastable Li-ion battery anode with pseudocapacitance-boosted electrochemical kinetics
In order to develop promising anode materials for lithium-ion batteries (LIBs), a unique nanocomposite abbreviated as G⊥FP@C-NA, in which a carbon-coated FeP nanorod array (FP@C-NA) is vertically grown on a conductive reduced graphene oxide (G) network, has been successfully prepared via a scalable...
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| Veröffentlicht in: | Nanoscale 2019-01, Vol.11 (3), p.1304-1312 |
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| creator | Hou, Bao-Hua Wang, Ying-Ying Ning, Qiu-Li Fan, Chao-Ying Xi, Xiao-Tong Yang, Xu Wang, Jiawei Zhang, Jing-Ping Wang, Xinlong Wu, Xing-Long |
| description | In order to develop promising anode materials for lithium-ion batteries (LIBs), a unique nanocomposite abbreviated as G⊥FP@C-NA, in which a carbon-coated FeP nanorod array (FP@C-NA) is vertically grown on a conductive reduced graphene oxide (G) network, has been successfully prepared via a scalable strategy. Benefiting from the distinctive structure, G⊥FP@C-NA exhibits much improved conductivity, structural stability and pseudocapacitance-boosted ultrafast electrochemical kinetics for Li storage. As a result, the G⊥FP@C-NA delivers a high Li-storage capacity (1106 mA h g-1 at 50 mA g-1), outstanding rate capability (565 mA h g-1 at 5000 mA g-1) and long-term cycling stability (1009 mA h g-1 at 500 mA g-1 after 500 cycles and 310 mA h g-1 at 2000 mA g-1 after 2000 cycles) when used as an anode material for LIBs. As expected, this kind of nanoarray structure is attractive and can also be extended to other electrode materials for various energy storage systems. |
| doi_str_mv | 10.1039/c8nr08849g |
| format | Article |
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Benefiting from the distinctive structure, G⊥FP@C-NA exhibits much improved conductivity, structural stability and pseudocapacitance-boosted ultrafast electrochemical kinetics for Li storage. As a result, the G⊥FP@C-NA delivers a high Li-storage capacity (1106 mA h g-1 at 50 mA g-1), outstanding rate capability (565 mA h g-1 at 5000 mA g-1) and long-term cycling stability (1009 mA h g-1 at 500 mA g-1 after 500 cycles and 310 mA h g-1 at 2000 mA g-1 after 2000 cycles) when used as an anode material for LIBs. As expected, this kind of nanoarray structure is attractive and can also be extended to other electrode materials for various energy storage systems.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/c8nr08849g</identifier><identifier>PMID: 30603754</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Anodes ; Electrode materials ; Energy storage ; Graphene ; Lithium ; Lithium-ion batteries ; Nanocomposites ; Nanorods ; Nanosheets ; Rechargeable batteries ; Storage capacity ; Storage systems ; Structural stability</subject><ispartof>Nanoscale, 2019-01, Vol.11 (3), p.1304-1312</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c269t-89ec1181d5c2676aff218d1275d1c9b96e89e0532cef50c5128788caaed989603</citedby><cites>FETCH-LOGICAL-c269t-89ec1181d5c2676aff218d1275d1c9b96e89e0532cef50c5128788caaed989603</cites><orcidid>0000-0003-3411-6186 ; 0000-0003-1069-9145 ; 0000-0002-5758-6351</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30603754$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hou, Bao-Hua</creatorcontrib><creatorcontrib>Wang, Ying-Ying</creatorcontrib><creatorcontrib>Ning, Qiu-Li</creatorcontrib><creatorcontrib>Fan, Chao-Ying</creatorcontrib><creatorcontrib>Xi, Xiao-Tong</creatorcontrib><creatorcontrib>Yang, Xu</creatorcontrib><creatorcontrib>Wang, Jiawei</creatorcontrib><creatorcontrib>Zhang, Jing-Ping</creatorcontrib><creatorcontrib>Wang, Xinlong</creatorcontrib><creatorcontrib>Wu, Xing-Long</creatorcontrib><title>An FeP@C nanoarray vertically grown on graphene nanosheets: an ultrastable Li-ion battery anode with pseudocapacitance-boosted electrochemical kinetics</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>In order to develop promising anode materials for lithium-ion batteries (LIBs), a unique nanocomposite abbreviated as G⊥FP@C-NA, in which a carbon-coated FeP nanorod array (FP@C-NA) is vertically grown on a conductive reduced graphene oxide (G) network, has been successfully prepared via a scalable strategy. Benefiting from the distinctive structure, G⊥FP@C-NA exhibits much improved conductivity, structural stability and pseudocapacitance-boosted ultrafast electrochemical kinetics for Li storage. As a result, the G⊥FP@C-NA delivers a high Li-storage capacity (1106 mA h g-1 at 50 mA g-1), outstanding rate capability (565 mA h g-1 at 5000 mA g-1) and long-term cycling stability (1009 mA h g-1 at 500 mA g-1 after 500 cycles and 310 mA h g-1 at 2000 mA g-1 after 2000 cycles) when used as an anode material for LIBs. As expected, this kind of nanoarray structure is attractive and can also be extended to other electrode materials for various energy storage systems.</description><subject>Anodes</subject><subject>Electrode materials</subject><subject>Energy storage</subject><subject>Graphene</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Nanocomposites</subject><subject>Nanorods</subject><subject>Nanosheets</subject><subject>Rechargeable batteries</subject><subject>Storage capacity</subject><subject>Storage systems</subject><subject>Structural stability</subject><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpd0c1O3DAQB3CrApWvXngAZIkLqhSw48Sxe-pqVSjSChCi52jiTNjQrJ3aDmifhNetl68DJ4_ln2cs_wk55OyUM6HPjLKeKVXo-y9kN2cFy4So8q2PWhY7ZC-EB8akFlJ8JTuCSSaqstglzzNLz_Hm55xasA68hzV9RB97A8OwpvfePVnqbCpgXKLFFxaWiDH8oGDpNEQPIUIzIF30WZ9oAzGiX6dT1yJ96uOSjgGn1hkYwfQRrMGscS5EbCkOaKJ3ZomrzUj6t7eYhocDst3BEPDb27pP_pz_upv_zhbXF5fz2SIzudQxUxoN54q3ZdpXErou56rleVW23OhGS0yClSI32JXMlDxXlVIGAFutdPqEfXLy2nf07t-EIdarPhgcBrDoplDnXArG0iWR6PEn-uAmb9PrNqpSpWaFTOr7qzLeheCxq0ffr8Cva87qTVz1XF3dvsR1kfDRW8upWWH7Qd_zEf8Bf4uSYA</recordid><startdate>20190117</startdate><enddate>20190117</enddate><creator>Hou, Bao-Hua</creator><creator>Wang, Ying-Ying</creator><creator>Ning, Qiu-Li</creator><creator>Fan, Chao-Ying</creator><creator>Xi, Xiao-Tong</creator><creator>Yang, Xu</creator><creator>Wang, Jiawei</creator><creator>Zhang, Jing-Ping</creator><creator>Wang, Xinlong</creator><creator>Wu, Xing-Long</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-3411-6186</orcidid><orcidid>https://orcid.org/0000-0003-1069-9145</orcidid><orcidid>https://orcid.org/0000-0002-5758-6351</orcidid></search><sort><creationdate>20190117</creationdate><title>An FeP@C nanoarray vertically grown on graphene nanosheets: an ultrastable Li-ion battery anode with pseudocapacitance-boosted electrochemical kinetics</title><author>Hou, Bao-Hua ; Wang, Ying-Ying ; Ning, Qiu-Li ; Fan, Chao-Ying ; Xi, Xiao-Tong ; Yang, Xu ; Wang, Jiawei ; Zhang, Jing-Ping ; Wang, Xinlong ; Wu, Xing-Long</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c269t-89ec1181d5c2676aff218d1275d1c9b96e89e0532cef50c5128788caaed989603</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Anodes</topic><topic>Electrode materials</topic><topic>Energy storage</topic><topic>Graphene</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Nanocomposites</topic><topic>Nanorods</topic><topic>Nanosheets</topic><topic>Rechargeable batteries</topic><topic>Storage capacity</topic><topic>Storage systems</topic><topic>Structural stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hou, Bao-Hua</creatorcontrib><creatorcontrib>Wang, Ying-Ying</creatorcontrib><creatorcontrib>Ning, Qiu-Li</creatorcontrib><creatorcontrib>Fan, Chao-Ying</creatorcontrib><creatorcontrib>Xi, Xiao-Tong</creatorcontrib><creatorcontrib>Yang, Xu</creatorcontrib><creatorcontrib>Wang, Jiawei</creatorcontrib><creatorcontrib>Zhang, Jing-Ping</creatorcontrib><creatorcontrib>Wang, Xinlong</creatorcontrib><creatorcontrib>Wu, Xing-Long</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hou, Bao-Hua</au><au>Wang, Ying-Ying</au><au>Ning, Qiu-Li</au><au>Fan, Chao-Ying</au><au>Xi, Xiao-Tong</au><au>Yang, Xu</au><au>Wang, Jiawei</au><au>Zhang, Jing-Ping</au><au>Wang, Xinlong</au><au>Wu, Xing-Long</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An FeP@C nanoarray vertically grown on graphene nanosheets: an ultrastable Li-ion battery anode with pseudocapacitance-boosted electrochemical kinetics</atitle><jtitle>Nanoscale</jtitle><addtitle>Nanoscale</addtitle><date>2019-01-17</date><risdate>2019</risdate><volume>11</volume><issue>3</issue><spage>1304</spage><epage>1312</epage><pages>1304-1312</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>In order to develop promising anode materials for lithium-ion batteries (LIBs), a unique nanocomposite abbreviated as G⊥FP@C-NA, in which a carbon-coated FeP nanorod array (FP@C-NA) is vertically grown on a conductive reduced graphene oxide (G) network, has been successfully prepared via a scalable strategy. Benefiting from the distinctive structure, G⊥FP@C-NA exhibits much improved conductivity, structural stability and pseudocapacitance-boosted ultrafast electrochemical kinetics for Li storage. As a result, the G⊥FP@C-NA delivers a high Li-storage capacity (1106 mA h g-1 at 50 mA g-1), outstanding rate capability (565 mA h g-1 at 5000 mA g-1) and long-term cycling stability (1009 mA h g-1 at 500 mA g-1 after 500 cycles and 310 mA h g-1 at 2000 mA g-1 after 2000 cycles) when used as an anode material for LIBs. As expected, this kind of nanoarray structure is attractive and can also be extended to other electrode materials for various energy storage systems.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30603754</pmid><doi>10.1039/c8nr08849g</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0003-3411-6186</orcidid><orcidid>https://orcid.org/0000-0003-1069-9145</orcidid><orcidid>https://orcid.org/0000-0002-5758-6351</orcidid></addata></record> |
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Anodes Electrode materials Energy storage Graphene Lithium Lithium-ion batteries Nanocomposites Nanorods Nanosheets Rechargeable batteries Storage capacity Storage systems Structural stability |
| title | An FeP@C nanoarray vertically grown on graphene nanosheets: an ultrastable Li-ion battery anode with pseudocapacitance-boosted electrochemical kinetics |
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