Understanding the effects of ionic liquids on a unimolecular substitution process: correlating solvent parameters with reaction outcome

A unimolecular substitution process was studied in five different ionic liquids, with systematic variation of either the cation or anion, in order to determine the factors leading to the increase in the rate constant for the process relative to acetonitrile. It was found that both components of the...

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Veröffentlicht in:	Organic & biomolecular chemistry 2019-01, Vol.17 (3), p.675-682
Hauptverfasser:	Gilbert, Alyssa, Haines, Ronald S, Harper, Jason B
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Correlation Data processing Dependence Ionic liquids Ions NMR Nuclear magnetic resonance Process parameters Rate constants Reaction mechanisms Solvents Substitution reactions
Online-Zugang:	Volltext
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