Sulfilimines as Versatile Nitrene Transfer Reagents: Facile Access to Diverse Aza‐Heterocycles

We herein report the unprecedented synthesis of diverse biologically important aza‐heterocycles by employing sulfilimines as nitrene transfer reagents. This class of sulfur‐based aza‐ylides had not been successfully used for gold nitrene transfer before. This work contains an efficient generation of...

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Veröffentlicht in:	Angewandte Chemie International Edition 2019-03, Vol.58 (11), p.3589-3593
Hauptverfasser:	Tian, Xianhai, Song, Lina, Rudolph, Matthias, Rominger, Frank, Oeser, Thomas, Hashmi, A. Stephen K.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Alkynes Carbenes cyclopropanation C−H annulation Gold gold carbenes gold catalysis Imines Indoles Reagents sulfilimines Sulfur Synthesis
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