Cesium-Incorporated Triple Cation Perovskites Deliver Fully Reversible and Stable Nanoscale Voltage Response

Cesium-Incorporated Triple Cation Perovskites Deliver Fully Reversible and Stable Nanoscale Voltage Response

Perovskite solar cells that incorporate small concentrations of Cs in their A-site have shown increased lifetime and improved device performance. Yet, the development of fully stable devices operating near the theoretical limit requires understanding how Cs influences perovskites’ electrical propert...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ACS nano 2019-02, Vol.13 (2), p.1538-1546, Article acsnano.8b07295
Hauptverfasser: Tennyson, Elizabeth M, Roose, Bart, Garrett, Joseph L, Gong, Chen, Munday, Jeremy N, Abate, Antonio, Leite, Marina S
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 1546
container_issue 2
container_start_page 1538
container_title ACS nano
container_volume 13
creator Tennyson, Elizabeth M
Roose, Bart
Garrett, Joseph L
Gong, Chen
Munday, Jeremy N
Abate, Antonio
Leite, Marina S
description Perovskite solar cells that incorporate small concentrations of Cs in their A-site have shown increased lifetime and improved device performance. Yet, the development of fully stable devices operating near the theoretical limit requires understanding how Cs influences perovskites’ electrical properties at the nanoscale. Here, we determine how the chemical composition of three perovskites (MAPbBr3, MAPbI3, and Cs-mixed) affects their short- and long-term voltage stabilities, with
doi_str_mv 10.1021/acsnano.8b07295
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2161064763</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2161064763</sourcerecordid><originalsourceid>FETCH-LOGICAL-a333t-25d627c6e50baaff5c3e1d939e7ce335911de209f42ccac29c1d2207efb09a113</originalsourceid><addsrcrecordid>eNp1kD1PwzAQhi0EoqUws6GMSCitP2onGVGhUKkCBAWxRY5zQSlOHOykUv89rhq6Md0zPPfq7kXokuAxwZRMpHK1rM04znBEE36EhiRhIsSx-Dw-MCcDdObcGmMexZE4RQOGeSw4ZkOkZ-DKrgoXtTK2MVa2kAcrWzYagplsS1MHL2DNxn2XLbjgDnS5ARvMO623wSt4dmXmXVnnwVsrd_jkD3JKevowupVf4D3XmNrBOToppHZw0c8Rep_fr2aP4fL5YTG7XYaSMdaGlOeCRkoAx5mURcEVA5InLIFIAWM8ISQHipNiSpWSiiaK5JTiCIoMJ5IQNkLX-9zGmp8OXJtWpVOgtazBdC6lRBAsppFgXp3sVWWNcxaKtLFlJe02JTjdVZz2Fad9xX7jqg_vsgryg__XqRdu9oLfTNems7X_9d-4Xzj1iV4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2161064763</pqid></control><display><type>article</type><title>Cesium-Incorporated Triple Cation Perovskites Deliver Fully Reversible and Stable Nanoscale Voltage Response</title><source>ACS Publications</source><creator>Tennyson, Elizabeth M ; Roose, Bart ; Garrett, Joseph L ; Gong, Chen ; Munday, Jeremy N ; Abate, Antonio ; Leite, Marina S</creator><creatorcontrib>Tennyson, Elizabeth M ; Roose, Bart ; Garrett, Joseph L ; Gong, Chen ; Munday, Jeremy N ; Abate, Antonio ; Leite, Marina S</creatorcontrib><description>Perovskite solar cells that incorporate small concentrations of Cs in their A-site have shown increased lifetime and improved device performance. Yet, the development of fully stable devices operating near the theoretical limit requires understanding how Cs influences perovskites’ electrical properties at the nanoscale. Here, we determine how the chemical composition of three perovskites (MAPbBr3, MAPbI3, and Cs-mixed) affects their short- and long-term voltage stabilities, with &lt;50 nm spatial resolution. We map an anomalous irreversible electrical signature on MAPbBr3 at the mesoscale, resulting in local V oc variations of ∼400 mV, and in entire grains with negative contribution to the V oc . These measurements prove the necessity of high spatial resolution mapping to elucidate the fundamental limitations of this emerging material. Conversely, we capture the fully reversible voltage response of Cs-mixed perovskites, composed by Cs0.06(MA0.17FA0.83)0.94Pb­(I0.83Br0.17)3, demonstrating that the desired electrical output persists even at the nanoscale. The Cs-mixed material presents no spatial variation in V oc , as ion motion is restricted. Our results show that the nanoscale electrical behavior of the perovskites is intimately connected to their chemical composition and macroscopic response.</description><identifier>ISSN: 1936-0851</identifier><identifier>EISSN: 1936-086X</identifier><identifier>DOI: 10.1021/acsnano.8b07295</identifier><identifier>PMID: 30586503</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>ACS nano, 2019-02, Vol.13 (2), p.1538-1546, Article acsnano.8b07295</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a333t-25d627c6e50baaff5c3e1d939e7ce335911de209f42ccac29c1d2207efb09a113</citedby><cites>FETCH-LOGICAL-a333t-25d627c6e50baaff5c3e1d939e7ce335911de209f42ccac29c1d2207efb09a113</cites><orcidid>0000-0001-8265-0661 ; 0000-0003-3302-7675 ; 0000-0003-0071-8445 ; 0000-0003-4888-8195 ; 0000-0002-0972-1475 ; 0000-0002-0881-9876</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acsnano.8b07295$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acsnano.8b07295$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2751,27055,27903,27904,56716,56766</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30586503$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Tennyson, Elizabeth M</creatorcontrib><creatorcontrib>Roose, Bart</creatorcontrib><creatorcontrib>Garrett, Joseph L</creatorcontrib><creatorcontrib>Gong, Chen</creatorcontrib><creatorcontrib>Munday, Jeremy N</creatorcontrib><creatorcontrib>Abate, Antonio</creatorcontrib><creatorcontrib>Leite, Marina S</creatorcontrib><title>Cesium-Incorporated Triple Cation Perovskites Deliver Fully Reversible and Stable Nanoscale Voltage Response</title><title>ACS nano</title><addtitle>ACS Nano</addtitle><description>Perovskite solar cells that incorporate small concentrations of Cs in their A-site have shown increased lifetime and improved device performance. Yet, the development of fully stable devices operating near the theoretical limit requires understanding how Cs influences perovskites’ electrical properties at the nanoscale. Here, we determine how the chemical composition of three perovskites (MAPbBr3, MAPbI3, and Cs-mixed) affects their short- and long-term voltage stabilities, with &lt;50 nm spatial resolution. We map an anomalous irreversible electrical signature on MAPbBr3 at the mesoscale, resulting in local V oc variations of ∼400 mV, and in entire grains with negative contribution to the V oc . These measurements prove the necessity of high spatial resolution mapping to elucidate the fundamental limitations of this emerging material. Conversely, we capture the fully reversible voltage response of Cs-mixed perovskites, composed by Cs0.06(MA0.17FA0.83)0.94Pb­(I0.83Br0.17)3, demonstrating that the desired electrical output persists even at the nanoscale. The Cs-mixed material presents no spatial variation in V oc , as ion motion is restricted. Our results show that the nanoscale electrical behavior of the perovskites is intimately connected to their chemical composition and macroscopic response.</description><issn>1936-0851</issn><issn>1936-086X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kD1PwzAQhi0EoqUws6GMSCitP2onGVGhUKkCBAWxRY5zQSlOHOykUv89rhq6Md0zPPfq7kXokuAxwZRMpHK1rM04znBEE36EhiRhIsSx-Dw-MCcDdObcGmMexZE4RQOGeSw4ZkOkZ-DKrgoXtTK2MVa2kAcrWzYagplsS1MHL2DNxn2XLbjgDnS5ARvMO623wSt4dmXmXVnnwVsrd_jkD3JKevowupVf4D3XmNrBOToppHZw0c8Rep_fr2aP4fL5YTG7XYaSMdaGlOeCRkoAx5mURcEVA5InLIFIAWM8ISQHipNiSpWSiiaK5JTiCIoMJ5IQNkLX-9zGmp8OXJtWpVOgtazBdC6lRBAsppFgXp3sVWWNcxaKtLFlJe02JTjdVZz2Fad9xX7jqg_vsgryg__XqRdu9oLfTNems7X_9d-4Xzj1iV4</recordid><startdate>20190226</startdate><enddate>20190226</enddate><creator>Tennyson, Elizabeth M</creator><creator>Roose, Bart</creator><creator>Garrett, Joseph L</creator><creator>Gong, Chen</creator><creator>Munday, Jeremy N</creator><creator>Abate, Antonio</creator><creator>Leite, Marina S</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-8265-0661</orcidid><orcidid>https://orcid.org/0000-0003-3302-7675</orcidid><orcidid>https://orcid.org/0000-0003-0071-8445</orcidid><orcidid>https://orcid.org/0000-0003-4888-8195</orcidid><orcidid>https://orcid.org/0000-0002-0972-1475</orcidid><orcidid>https://orcid.org/0000-0002-0881-9876</orcidid></search><sort><creationdate>20190226</creationdate><title>Cesium-Incorporated Triple Cation Perovskites Deliver Fully Reversible and Stable Nanoscale Voltage Response</title><author>Tennyson, Elizabeth M ; Roose, Bart ; Garrett, Joseph L ; Gong, Chen ; Munday, Jeremy N ; Abate, Antonio ; Leite, Marina S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a333t-25d627c6e50baaff5c3e1d939e7ce335911de209f42ccac29c1d2207efb09a113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tennyson, Elizabeth M</creatorcontrib><creatorcontrib>Roose, Bart</creatorcontrib><creatorcontrib>Garrett, Joseph L</creatorcontrib><creatorcontrib>Gong, Chen</creatorcontrib><creatorcontrib>Munday, Jeremy N</creatorcontrib><creatorcontrib>Abate, Antonio</creatorcontrib><creatorcontrib>Leite, Marina S</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ACS nano</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tennyson, Elizabeth M</au><au>Roose, Bart</au><au>Garrett, Joseph L</au><au>Gong, Chen</au><au>Munday, Jeremy N</au><au>Abate, Antonio</au><au>Leite, Marina S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cesium-Incorporated Triple Cation Perovskites Deliver Fully Reversible and Stable Nanoscale Voltage Response</atitle><jtitle>ACS nano</jtitle><addtitle>ACS Nano</addtitle><date>2019-02-26</date><risdate>2019</risdate><volume>13</volume><issue>2</issue><spage>1538</spage><epage>1546</epage><pages>1538-1546</pages><artnum>acsnano.8b07295</artnum><issn>1936-0851</issn><eissn>1936-086X</eissn><abstract>Perovskite solar cells that incorporate small concentrations of Cs in their A-site have shown increased lifetime and improved device performance. Yet, the development of fully stable devices operating near the theoretical limit requires understanding how Cs influences perovskites’ electrical properties at the nanoscale. Here, we determine how the chemical composition of three perovskites (MAPbBr3, MAPbI3, and Cs-mixed) affects their short- and long-term voltage stabilities, with &lt;50 nm spatial resolution. We map an anomalous irreversible electrical signature on MAPbBr3 at the mesoscale, resulting in local V oc variations of ∼400 mV, and in entire grains with negative contribution to the V oc . These measurements prove the necessity of high spatial resolution mapping to elucidate the fundamental limitations of this emerging material. Conversely, we capture the fully reversible voltage response of Cs-mixed perovskites, composed by Cs0.06(MA0.17FA0.83)0.94Pb­(I0.83Br0.17)3, demonstrating that the desired electrical output persists even at the nanoscale. The Cs-mixed material presents no spatial variation in V oc , as ion motion is restricted. Our results show that the nanoscale electrical behavior of the perovskites is intimately connected to their chemical composition and macroscopic response.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>30586503</pmid><doi>10.1021/acsnano.8b07295</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-8265-0661</orcidid><orcidid>https://orcid.org/0000-0003-3302-7675</orcidid><orcidid>https://orcid.org/0000-0003-0071-8445</orcidid><orcidid>https://orcid.org/0000-0003-4888-8195</orcidid><orcidid>https://orcid.org/0000-0002-0972-1475</orcidid><orcidid>https://orcid.org/0000-0002-0881-9876</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1936-0851
ispartof ACS nano, 2019-02, Vol.13 (2), p.1538-1546, Article acsnano.8b07295
issn 1936-0851
1936-086X
language eng
recordid cdi_proquest_miscellaneous_2161064763
source ACS Publications
title Cesium-Incorporated Triple Cation Perovskites Deliver Fully Reversible and Stable Nanoscale Voltage Response
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-26T05%3A51%3A40IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Cesium-Incorporated%20Triple%20Cation%20Perovskites%20Deliver%20Fully%20Reversible%20and%20Stable%20Nanoscale%20Voltage%20Response&rft.jtitle=ACS%20nano&rft.au=Tennyson,%20Elizabeth%20M&rft.date=2019-02-26&rft.volume=13&rft.issue=2&rft.spage=1538&rft.epage=1546&rft.pages=1538-1546&rft.artnum=acsnano.8b07295&rft.issn=1936-0851&rft.eissn=1936-086X&rft_id=info:doi/10.1021/acsnano.8b07295&rft_dat=%3Cproquest_cross%3E2161064763%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2161064763&rft_id=info:pmid/30586503&rfr_iscdi=true