Benzoic acid as a selector-modulator in the synthesis of MIL-88B(Cr) and nano-MIL-101(Cr)
The concentration of benzoic acid was found to exercise efficient control over the formation of either MIL-101(Cr) or MIL-88B(Cr) under otherwise similar hydrothermal synthetic conditions. Nanocrystals of MIL-101(Cr) with ∼100 nm average size and excellent S BET = 3467 m 2 g −1 are obtained at lower...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2019-01, Vol.48 (3), p.989-996 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 48 |
| creator | Yang, Ling Zhao, Tian Boldog, Ishtvan Janiak, Christoph Yang, Xiao-Yu Li, Qiang Zhou, Yan-Jia Xia, Yong Lai, Deng-Wang Liu, Yue-Jun |
| description | The concentration of benzoic acid was found to exercise efficient control over the formation of either MIL-101(Cr) or MIL-88B(Cr) under otherwise similar hydrothermal synthetic conditions. Nanocrystals of MIL-101(Cr) with ∼100 nm average size and excellent
S
BET
= 3467 m
2
g
−1
are obtained at lower concentrations of benzoic acid, while at higher concentrations the microparticulated MIL-88B(Cr) product is formed. Hereby a new efficient synthetic method towards the elusive MIL-88B(Cr), yet reported only once without synthetic details, is proposed. The obtained MIL-88B(Cr) has an interesting and potentially valuable property of retaining its high-volume form (
V
cell
∼ 2000 Å
3
) after thermal activation. The degassing of MIL-88B(Cr) in a vacuum at 250 °C yields a porous material with a
S
BET
area of 1136 m
2
g
−1
, which is around the theoretical maximum. The transition to the denser 'closed' form (
V
cell
∼ 1500 Å
3
) occurs only at 350 °C, when all of the benzoate/benzoic acid, hindering the process, is removed.
The concentration of benzoic acid was found to exercise efficient control over the formation of either MIL-101(Cr) or MIL-88B(Cr) under otherwise similar hydrothermal synthetic conditions. |
| doi_str_mv | 10.1039/c8dt04186e |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_proquest_miscellaneous_2159983098</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2159983098</sourcerecordid><originalsourceid>FETCH-LOGICAL-c337t-bf78ce5e550c47849039a883c150890528906af28c11e1e051be2c012a2ab1853</originalsourceid><addsrcrecordid>eNpdkT1PwzAQhi0EoqWwsIMssRSkgD_i2BlpKFCpiKUMTJHjOCJVYhc7Gcqvx6WlSAz3obtHp7v3ADjH6BYjmt4pUXYoxiLRB2CIY86jlND4cJ-TZABOvF8iRAhi5BgMKGI8ThkfgveJNl-2VlCquoTSQwm9brTqrItaW_aNDBmsDew-NPRrE4KvPbQVfJnNIyEm48xdQ2lKaKSx0aaIEd4UT8FRJRuvz3ZxBN4ep4vsOZq_Ps2y-3mkKOVdVFRcKM00Y0jFXMRpuEgKQRVmSKRh3eASWRGhMNZYI4YLTRTCRBJZYMHoCIy3c1fOfvbad3lbe6WbRhpte58TzNJUUBRsBK7-oUvbOxO2C1TCUUyDVoG62VLKWe-drvKVq1vp1jlG-UbwPBMPix_BpwG-3I3si1aXe_RX4QBcbAHn1b779zH6DcNef_Y</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2167043226</pqid></control><display><type>article</type><title>Benzoic acid as a selector-modulator in the synthesis of MIL-88B(Cr) and nano-MIL-101(Cr)</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Yang, Ling ; Zhao, Tian ; Boldog, Ishtvan ; Janiak, Christoph ; Yang, Xiao-Yu ; Li, Qiang ; Zhou, Yan-Jia ; Xia, Yong ; Lai, Deng-Wang ; Liu, Yue-Jun</creator><creatorcontrib>Yang, Ling ; Zhao, Tian ; Boldog, Ishtvan ; Janiak, Christoph ; Yang, Xiao-Yu ; Li, Qiang ; Zhou, Yan-Jia ; Xia, Yong ; Lai, Deng-Wang ; Liu, Yue-Jun</creatorcontrib><description>The concentration of benzoic acid was found to exercise efficient control over the formation of either MIL-101(Cr) or MIL-88B(Cr) under otherwise similar hydrothermal synthetic conditions. Nanocrystals of MIL-101(Cr) with ∼100 nm average size and excellent
S
BET
= 3467 m
2
g
−1
are obtained at lower concentrations of benzoic acid, while at higher concentrations the microparticulated MIL-88B(Cr) product is formed. Hereby a new efficient synthetic method towards the elusive MIL-88B(Cr), yet reported only once without synthetic details, is proposed. The obtained MIL-88B(Cr) has an interesting and potentially valuable property of retaining its high-volume form (
V
cell
∼ 2000 Å
3
) after thermal activation. The degassing of MIL-88B(Cr) in a vacuum at 250 °C yields a porous material with a
S
BET
area of 1136 m
2
g
−1
, which is around the theoretical maximum. The transition to the denser 'closed' form (
V
cell
∼ 1500 Å
3
) occurs only at 350 °C, when all of the benzoate/benzoic acid, hindering the process, is removed.
The concentration of benzoic acid was found to exercise efficient control over the formation of either MIL-101(Cr) or MIL-88B(Cr) under otherwise similar hydrothermal synthetic conditions.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c8dt04186e</identifier><identifier>PMID: 30574957</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Acids ; Benzoic acid ; Degassing ; Nanocrystals ; Porous materials</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2019-01, Vol.48 (3), p.989-996</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-bf78ce5e550c47849039a883c150890528906af28c11e1e051be2c012a2ab1853</citedby><cites>FETCH-LOGICAL-c337t-bf78ce5e550c47849039a883c150890528906af28c11e1e051be2c012a2ab1853</cites><orcidid>0000-0003-3454-3604 ; 0000-0003-0745-1405 ; 0000-0003-3092-2113 ; 0000-0001-6077-4524 ; 0000-0002-6288-9605</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30574957$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yang, Ling</creatorcontrib><creatorcontrib>Zhao, Tian</creatorcontrib><creatorcontrib>Boldog, Ishtvan</creatorcontrib><creatorcontrib>Janiak, Christoph</creatorcontrib><creatorcontrib>Yang, Xiao-Yu</creatorcontrib><creatorcontrib>Li, Qiang</creatorcontrib><creatorcontrib>Zhou, Yan-Jia</creatorcontrib><creatorcontrib>Xia, Yong</creatorcontrib><creatorcontrib>Lai, Deng-Wang</creatorcontrib><creatorcontrib>Liu, Yue-Jun</creatorcontrib><title>Benzoic acid as a selector-modulator in the synthesis of MIL-88B(Cr) and nano-MIL-101(Cr)</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>The concentration of benzoic acid was found to exercise efficient control over the formation of either MIL-101(Cr) or MIL-88B(Cr) under otherwise similar hydrothermal synthetic conditions. Nanocrystals of MIL-101(Cr) with ∼100 nm average size and excellent
S
BET
= 3467 m
2
g
−1
are obtained at lower concentrations of benzoic acid, while at higher concentrations the microparticulated MIL-88B(Cr) product is formed. Hereby a new efficient synthetic method towards the elusive MIL-88B(Cr), yet reported only once without synthetic details, is proposed. The obtained MIL-88B(Cr) has an interesting and potentially valuable property of retaining its high-volume form (
V
cell
∼ 2000 Å
3
) after thermal activation. The degassing of MIL-88B(Cr) in a vacuum at 250 °C yields a porous material with a
S
BET
area of 1136 m
2
g
−1
, which is around the theoretical maximum. The transition to the denser 'closed' form (
V
cell
∼ 1500 Å
3
) occurs only at 350 °C, when all of the benzoate/benzoic acid, hindering the process, is removed.
The concentration of benzoic acid was found to exercise efficient control over the formation of either MIL-101(Cr) or MIL-88B(Cr) under otherwise similar hydrothermal synthetic conditions.</description><subject>Acids</subject><subject>Benzoic acid</subject><subject>Degassing</subject><subject>Nanocrystals</subject><subject>Porous materials</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpdkT1PwzAQhi0EoqWwsIMssRSkgD_i2BlpKFCpiKUMTJHjOCJVYhc7Gcqvx6WlSAz3obtHp7v3ADjH6BYjmt4pUXYoxiLRB2CIY86jlND4cJ-TZABOvF8iRAhi5BgMKGI8ThkfgveJNl-2VlCquoTSQwm9brTqrItaW_aNDBmsDew-NPRrE4KvPbQVfJnNIyEm48xdQ2lKaKSx0aaIEd4UT8FRJRuvz3ZxBN4ep4vsOZq_Ps2y-3mkKOVdVFRcKM00Y0jFXMRpuEgKQRVmSKRh3eASWRGhMNZYI4YLTRTCRBJZYMHoCIy3c1fOfvbad3lbe6WbRhpte58TzNJUUBRsBK7-oUvbOxO2C1TCUUyDVoG62VLKWe-drvKVq1vp1jlG-UbwPBMPix_BpwG-3I3si1aXe_RX4QBcbAHn1b779zH6DcNef_Y</recordid><startdate>20190115</startdate><enddate>20190115</enddate><creator>Yang, Ling</creator><creator>Zhao, Tian</creator><creator>Boldog, Ishtvan</creator><creator>Janiak, Christoph</creator><creator>Yang, Xiao-Yu</creator><creator>Li, Qiang</creator><creator>Zhou, Yan-Jia</creator><creator>Xia, Yong</creator><creator>Lai, Deng-Wang</creator><creator>Liu, Yue-Jun</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-3454-3604</orcidid><orcidid>https://orcid.org/0000-0003-0745-1405</orcidid><orcidid>https://orcid.org/0000-0003-3092-2113</orcidid><orcidid>https://orcid.org/0000-0001-6077-4524</orcidid><orcidid>https://orcid.org/0000-0002-6288-9605</orcidid></search><sort><creationdate>20190115</creationdate><title>Benzoic acid as a selector-modulator in the synthesis of MIL-88B(Cr) and nano-MIL-101(Cr)</title><author>Yang, Ling ; Zhao, Tian ; Boldog, Ishtvan ; Janiak, Christoph ; Yang, Xiao-Yu ; Li, Qiang ; Zhou, Yan-Jia ; Xia, Yong ; Lai, Deng-Wang ; Liu, Yue-Jun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-bf78ce5e550c47849039a883c150890528906af28c11e1e051be2c012a2ab1853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Acids</topic><topic>Benzoic acid</topic><topic>Degassing</topic><topic>Nanocrystals</topic><topic>Porous materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Ling</creatorcontrib><creatorcontrib>Zhao, Tian</creatorcontrib><creatorcontrib>Boldog, Ishtvan</creatorcontrib><creatorcontrib>Janiak, Christoph</creatorcontrib><creatorcontrib>Yang, Xiao-Yu</creatorcontrib><creatorcontrib>Li, Qiang</creatorcontrib><creatorcontrib>Zhou, Yan-Jia</creatorcontrib><creatorcontrib>Xia, Yong</creatorcontrib><creatorcontrib>Lai, Deng-Wang</creatorcontrib><creatorcontrib>Liu, Yue-Jun</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Ling</au><au>Zhao, Tian</au><au>Boldog, Ishtvan</au><au>Janiak, Christoph</au><au>Yang, Xiao-Yu</au><au>Li, Qiang</au><au>Zhou, Yan-Jia</au><au>Xia, Yong</au><au>Lai, Deng-Wang</au><au>Liu, Yue-Jun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Benzoic acid as a selector-modulator in the synthesis of MIL-88B(Cr) and nano-MIL-101(Cr)</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2019-01-15</date><risdate>2019</risdate><volume>48</volume><issue>3</issue><spage>989</spage><epage>996</epage><pages>989-996</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>The concentration of benzoic acid was found to exercise efficient control over the formation of either MIL-101(Cr) or MIL-88B(Cr) under otherwise similar hydrothermal synthetic conditions. Nanocrystals of MIL-101(Cr) with ∼100 nm average size and excellent
S
BET
= 3467 m
2
g
−1
are obtained at lower concentrations of benzoic acid, while at higher concentrations the microparticulated MIL-88B(Cr) product is formed. Hereby a new efficient synthetic method towards the elusive MIL-88B(Cr), yet reported only once without synthetic details, is proposed. The obtained MIL-88B(Cr) has an interesting and potentially valuable property of retaining its high-volume form (
V
cell
∼ 2000 Å
3
) after thermal activation. The degassing of MIL-88B(Cr) in a vacuum at 250 °C yields a porous material with a
S
BET
area of 1136 m
2
g
−1
, which is around the theoretical maximum. The transition to the denser 'closed' form (
V
cell
∼ 1500 Å
3
) occurs only at 350 °C, when all of the benzoate/benzoic acid, hindering the process, is removed.
The concentration of benzoic acid was found to exercise efficient control over the formation of either MIL-101(Cr) or MIL-88B(Cr) under otherwise similar hydrothermal synthetic conditions.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30574957</pmid><doi>10.1039/c8dt04186e</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-3454-3604</orcidid><orcidid>https://orcid.org/0000-0003-0745-1405</orcidid><orcidid>https://orcid.org/0000-0003-3092-2113</orcidid><orcidid>https://orcid.org/0000-0001-6077-4524</orcidid><orcidid>https://orcid.org/0000-0002-6288-9605</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2019-01, Vol.48 (3), p.989-996 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2159983098 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Acids Benzoic acid Degassing Nanocrystals Porous materials |
| title | Benzoic acid as a selector-modulator in the synthesis of MIL-88B(Cr) and nano-MIL-101(Cr) |
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