Hierarchy of Asymmetry in Chiral Supramolecular Polymers: Toward Functional, Helical Supramolecular Structures
The formation of helical structures through the supramolecular polymerization of a variety of self‐assembling units is reviewed. These scaffolds are usually obtained by efficient transfer or amplification of chirality phenomena, in which the starting self‐assembling molecules possess different eleme...
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| Veröffentlicht in: | Chemistry : a European journal 2019-04, Vol.25 (23), p.5848-5864 |
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| container_title | Chemistry : a European journal |
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| creator | Dorca, Yeray Greciano, Elisa E. Valera, Jorge S. Gómez, Rafael Sánchez, Luis |
| description | The formation of helical structures through the supramolecular polymerization of a variety of self‐assembling units is reviewed. These scaffolds are usually obtained by efficient transfer or amplification of chirality phenomena, in which the starting self‐assembling molecules possess different elements of asymmetry, such as point or axial chirality. Relevant examples of helical supramolecular structures investigated under thermodynamic control are reviewed, and the helical outcome of remarkable examples of chiral entities obtained through kinetic control are also highlighted. Finally, selected examples of flexible macroscopic chirality and catalysis are described to illustrate the applicability of helical aggregates.
Twist formation: The formation of helical structures through the supramolecular polymerization of a variety of self‐assembling units with different elements of asymmetry is reviewed (see figure). Examples of helical supramolecular structures obtained under thermodynamic control and other remarkable examples of chiral entities obtained through kinetic control are given. Finally, examples of flexible macroscopic chirality and catalysis are described. |
| doi_str_mv | 10.1002/chem.201805577 |
| format | Article |
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Twist formation: The formation of helical structures through the supramolecular polymerization of a variety of self‐assembling units with different elements of asymmetry is reviewed (see figure). Examples of helical supramolecular structures obtained under thermodynamic control and other remarkable examples of chiral entities obtained through kinetic control are given. Finally, examples of flexible macroscopic chirality and catalysis are described.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201805577</identifier><identifier>PMID: 30561853</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Asymmetry ; Catalysis ; Chemistry ; Chirality ; helical structures ; Polymerization ; Polymers ; Reviews ; self-assembly ; supramolecular chemistry ; Supramolecular polymers</subject><ispartof>Chemistry : a European journal, 2019-04, Vol.25 (23), p.5848-5864</ispartof><rights>2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4767-a1bf1c43d3cbed9797a1501f01bb6de5664eb1288708e9b58ad06a603f21f1a13</citedby><cites>FETCH-LOGICAL-c4767-a1bf1c43d3cbed9797a1501f01bb6de5664eb1288708e9b58ad06a603f21f1a13</cites><orcidid>0000-0001-7867-8522</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201805577$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201805577$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30561853$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dorca, Yeray</creatorcontrib><creatorcontrib>Greciano, Elisa E.</creatorcontrib><creatorcontrib>Valera, Jorge S.</creatorcontrib><creatorcontrib>Gómez, Rafael</creatorcontrib><creatorcontrib>Sánchez, Luis</creatorcontrib><title>Hierarchy of Asymmetry in Chiral Supramolecular Polymers: Toward Functional, Helical Supramolecular Structures</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>The formation of helical structures through the supramolecular polymerization of a variety of self‐assembling units is reviewed. These scaffolds are usually obtained by efficient transfer or amplification of chirality phenomena, in which the starting self‐assembling molecules possess different elements of asymmetry, such as point or axial chirality. Relevant examples of helical supramolecular structures investigated under thermodynamic control are reviewed, and the helical outcome of remarkable examples of chiral entities obtained through kinetic control are also highlighted. Finally, selected examples of flexible macroscopic chirality and catalysis are described to illustrate the applicability of helical aggregates.
Twist formation: The formation of helical structures through the supramolecular polymerization of a variety of self‐assembling units with different elements of asymmetry is reviewed (see figure). Examples of helical supramolecular structures obtained under thermodynamic control and other remarkable examples of chiral entities obtained through kinetic control are given. Finally, examples of flexible macroscopic chirality and catalysis are described.</description><subject>Asymmetry</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Chirality</subject><subject>helical structures</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Reviews</subject><subject>self-assembly</subject><subject>supramolecular chemistry</subject><subject>Supramolecular polymers</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqF0UFr3DAQBWBRWppN2muPRdBLDvVGI1mS1VtYkmwgJYWkZyPLY9ZBtraSRfC_r8OmKbSHnObyzYOZR8gnYGtgjJ-5HQ5rzqBiUmr9hqxAciiEVvItWTFT6kJJYY7IcUoPjDGjhHhPjgSTCiopVmTc9hhtdLuZho6ep3kYcIoz7Ue62fXRenqX99EOwaPL3kb6I_h5wJi-0fvwaGNLL_Popj6M1n-lW_S9-3_nborZTTli-kDeddYn_Pg8T8jPy4v7zba4ub263pzfFK7UShcWmg5cKVrhGmyNNtqCZNAxaBrVolSqxAZ4VWlWoWlkZVumrGKi49CBBXFCTg-5-xh-ZUxTPfTJofd2xJBTzUFWvBRcm4V--Yc-hByXcxbFgWtmRCkWtT4oF0NKEbt6H_vBxrkGVj81UT81Ub80sSx8fo7NzYDtC__z-gWYA3jsPc6vxNWb7cX3v-G_AbT7lh0</recordid><startdate>20190423</startdate><enddate>20190423</enddate><creator>Dorca, Yeray</creator><creator>Greciano, Elisa E.</creator><creator>Valera, Jorge S.</creator><creator>Gómez, Rafael</creator><creator>Sánchez, Luis</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-7867-8522</orcidid></search><sort><creationdate>20190423</creationdate><title>Hierarchy of Asymmetry in Chiral Supramolecular Polymers: Toward Functional, Helical Supramolecular Structures</title><author>Dorca, Yeray ; Greciano, Elisa E. ; Valera, Jorge S. ; Gómez, Rafael ; Sánchez, Luis</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4767-a1bf1c43d3cbed9797a1501f01bb6de5664eb1288708e9b58ad06a603f21f1a13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Asymmetry</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Chirality</topic><topic>helical structures</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Reviews</topic><topic>self-assembly</topic><topic>supramolecular chemistry</topic><topic>Supramolecular polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dorca, Yeray</creatorcontrib><creatorcontrib>Greciano, Elisa E.</creatorcontrib><creatorcontrib>Valera, Jorge S.</creatorcontrib><creatorcontrib>Gómez, Rafael</creatorcontrib><creatorcontrib>Sánchez, Luis</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dorca, Yeray</au><au>Greciano, Elisa E.</au><au>Valera, Jorge S.</au><au>Gómez, Rafael</au><au>Sánchez, Luis</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hierarchy of Asymmetry in Chiral Supramolecular Polymers: Toward Functional, Helical Supramolecular Structures</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2019-04-23</date><risdate>2019</risdate><volume>25</volume><issue>23</issue><spage>5848</spage><epage>5864</epage><pages>5848-5864</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>The formation of helical structures through the supramolecular polymerization of a variety of self‐assembling units is reviewed. These scaffolds are usually obtained by efficient transfer or amplification of chirality phenomena, in which the starting self‐assembling molecules possess different elements of asymmetry, such as point or axial chirality. Relevant examples of helical supramolecular structures investigated under thermodynamic control are reviewed, and the helical outcome of remarkable examples of chiral entities obtained through kinetic control are also highlighted. Finally, selected examples of flexible macroscopic chirality and catalysis are described to illustrate the applicability of helical aggregates.
Twist formation: The formation of helical structures through the supramolecular polymerization of a variety of self‐assembling units with different elements of asymmetry is reviewed (see figure). Examples of helical supramolecular structures obtained under thermodynamic control and other remarkable examples of chiral entities obtained through kinetic control are given. Finally, examples of flexible macroscopic chirality and catalysis are described.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>30561853</pmid><doi>10.1002/chem.201805577</doi><tpages>17</tpages><orcidid>https://orcid.org/0000-0001-7867-8522</orcidid></addata></record> |
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| subjects | Asymmetry Catalysis Chemistry Chirality helical structures Polymerization Polymers Reviews self-assembly supramolecular chemistry Supramolecular polymers |
| title | Hierarchy of Asymmetry in Chiral Supramolecular Polymers: Toward Functional, Helical Supramolecular Structures |
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