Computational and experimental studies on copper-mediated selective cascade C-H/N-H annulation of electron-deficient acrylamide with arynes

An efficient and convenient copper-mediated method has been developed to achieve direct cascade C-H/N-H annulation to synthesize 2-quinolinones from electron-deficient acrylamides and arynes. This method highlights an emerging but simple strategy to transform inert C-H bonds into versatile functiona...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2019-01, Vol.55 (6), p.755-758
Hauptverfasser:	Chen, Chao, Hao, Yu, Zhang, Ting-Yu, Pan, Jin-Long, Ding, Jun, Xiang, Heng-Ye, Wang, Man, Ding, Tong-Mei, Duan, Abing, Zhang, Shu-Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Acrylamide Chemical reactions Copper Crystallography Density functional theory Functional groups NMR Nuclear magnetic resonance Organic chemistry Synthesis
Online-Zugang:	Volltext
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