Blue‐Light‐Induced Carbene‐Transfer Reactions of Diazoalkanes

Carbenes are very important reactive intermediates to access a variety of complex molecules and are applied widely in organic synthesis and drug discovery. Typically, their chemistry is accessed by the use of transition metal catalysts. Herein, we describe the application of low‐energy blue light fo...

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Veröffentlicht in:	Angewandte Chemie International Edition 2019-01, Vol.58 (4), p.1203-1207
Hauptverfasser:	Hommelsheim, Renè, Guo, Yujing, Yang, Zhen, Empel, Claire, Koenigs, Rene M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Atmospheric chemistry Carbenes Catalysis Catalysts Chemical synthesis continuous-flow cyclopropenation diazoalkanes Intermediates Organic chemistry Photochemicals photochemistry rearrangement Transition metals
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