Diphosphoniodiphosphene Formation by Transition Metal Insertion into a Triphosphenium Zwitterion
Treatment of two equivalents of the triphosphenium zwitterion L with sources of Ni0 and Pd0 form the mononuclear η2‐diphosphoniodiphosphene complexes 1 and 2. The reaction between L and [FeCp(CO)2]2 results in the binuclear μ‐η1:η1‐diphosphoniodiphosphene iron complex 3, which features an alternativ...
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| Veröffentlicht in: | Chemistry : a European journal 2019-01, Vol.25 (5), p.1208-1211 |
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| container_title | Chemistry : a European journal |
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| creator | Kosnik, Stephanie C. Binder, Justin F. Nascimento, Maxemilian C. Swidan, Ala'aeddeen Macdonald, Charles L. B. |
| description | Treatment of two equivalents of the triphosphenium zwitterion L with sources of Ni0 and Pd0 form the mononuclear η2‐diphosphoniodiphosphene complexes 1 and 2. The reaction between L and [FeCp(CO)2]2 results in the binuclear μ‐η1:η1‐diphosphoniodiphosphene iron complex 3, which features an alternative bonding motif of the diphosphoniodiphosphene unit. The formation of these species has been confirmed by spectroscopic methods and single‐crystal X‐ray diffraction analysis, and their electronic structures have been elucidated using computational methods.
A diphosphoniodiphosphene is unexpectedly formed by insertion of Ni0, Pd0, and FeI into the P−P bonds of a triphosphenium zwitterion, giving rise to structurally confirmed μ2‐bound monometallic or μ‐η1:η1‐bimetallic species. |
| doi_str_mv | 10.1002/chem.201805711 |
| format | Article |
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A diphosphoniodiphosphene is unexpectedly formed by insertion of Ni0, Pd0, and FeI into the P−P bonds of a triphosphenium zwitterion, giving rise to structurally confirmed μ2‐bound monometallic or μ‐η1:η1‐bimetallic species.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201805711</identifier><identifier>PMID: 30468552</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Chemistry ; Computer applications ; Crystal structure ; diphosphene ; insertion ; Iron ; oligophosphorus ; Palladium ; phosphorus ; Transition metals ; triphosphenium ; X-ray diffraction ; Zwitterions</subject><ispartof>Chemistry : a European journal, 2019-01, Vol.25 (5), p.1208-1211</ispartof><rights>2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4101-7d19f59e4f254e558cfffb71fab35de979cb557766cbc5de50c95fa1e10945fe3</citedby><cites>FETCH-LOGICAL-c4101-7d19f59e4f254e558cfffb71fab35de979cb557766cbc5de50c95fa1e10945fe3</cites><orcidid>0000-0002-0574-1524</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201805711$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201805711$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30468552$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kosnik, Stephanie C.</creatorcontrib><creatorcontrib>Binder, Justin F.</creatorcontrib><creatorcontrib>Nascimento, Maxemilian C.</creatorcontrib><creatorcontrib>Swidan, Ala'aeddeen</creatorcontrib><creatorcontrib>Macdonald, Charles L. B.</creatorcontrib><title>Diphosphoniodiphosphene Formation by Transition Metal Insertion into a Triphosphenium Zwitterion</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>Treatment of two equivalents of the triphosphenium zwitterion L with sources of Ni0 and Pd0 form the mononuclear η2‐diphosphoniodiphosphene complexes 1 and 2. The reaction between L and [FeCp(CO)2]2 results in the binuclear μ‐η1:η1‐diphosphoniodiphosphene iron complex 3, which features an alternative bonding motif of the diphosphoniodiphosphene unit. The formation of these species has been confirmed by spectroscopic methods and single‐crystal X‐ray diffraction analysis, and their electronic structures have been elucidated using computational methods.
A diphosphoniodiphosphene is unexpectedly formed by insertion of Ni0, Pd0, and FeI into the P−P bonds of a triphosphenium zwitterion, giving rise to structurally confirmed μ2‐bound monometallic or μ‐η1:η1‐bimetallic species.</description><subject>Chemistry</subject><subject>Computer applications</subject><subject>Crystal structure</subject><subject>diphosphene</subject><subject>insertion</subject><subject>Iron</subject><subject>oligophosphorus</subject><subject>Palladium</subject><subject>phosphorus</subject><subject>Transition metals</subject><subject>triphosphenium</subject><subject>X-ray diffraction</subject><subject>Zwitterions</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkLtPwzAQxi0EgvJYGVEkFpYUO7bjeETl0UpULGVhCY57FkZJXOxEVf973AdFYmE43UO_-3T3IXRJ8JBgnN3qD2iGGSYF5oKQAzQgPCMpFTk_RAMsmUhzTuUJOg3hE2Msc0qP0QnFLC84zwbo_d4uPlyI0Vo339XQQvLofKM669qkWiUzr9pgN90UOlUnkzaA3_S27VyiIrHftX2TvC1t14GPwDk6MqoOcLHLZ-j18WE2GqfPL0-T0d1zqhnBJBVzIg2XwEzGGXBeaGNMJYhRFeVzkELqinMh8lxXOg441pIbRYDEJ7kBeoZutroL7756CF3Z2KChrlULrg9lRqhgOaMFjuj1H_TT9b6N10VK4CJjpMgjNdxS2rsQPJhy4W2j_KokuFx7X669L_fex4WrnWxfNTDf4z9mR0BugaWtYfWPXDkaP0x_xb8BCoWSTQ</recordid><startdate>20190124</startdate><enddate>20190124</enddate><creator>Kosnik, Stephanie C.</creator><creator>Binder, Justin F.</creator><creator>Nascimento, Maxemilian C.</creator><creator>Swidan, Ala'aeddeen</creator><creator>Macdonald, Charles L. B.</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-0574-1524</orcidid></search><sort><creationdate>20190124</creationdate><title>Diphosphoniodiphosphene Formation by Transition Metal Insertion into a Triphosphenium Zwitterion</title><author>Kosnik, Stephanie C. ; Binder, Justin F. ; Nascimento, Maxemilian C. ; Swidan, Ala'aeddeen ; Macdonald, Charles L. B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4101-7d19f59e4f254e558cfffb71fab35de979cb557766cbc5de50c95fa1e10945fe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Chemistry</topic><topic>Computer applications</topic><topic>Crystal structure</topic><topic>diphosphene</topic><topic>insertion</topic><topic>Iron</topic><topic>oligophosphorus</topic><topic>Palladium</topic><topic>phosphorus</topic><topic>Transition metals</topic><topic>triphosphenium</topic><topic>X-ray diffraction</topic><topic>Zwitterions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kosnik, Stephanie C.</creatorcontrib><creatorcontrib>Binder, Justin F.</creatorcontrib><creatorcontrib>Nascimento, Maxemilian C.</creatorcontrib><creatorcontrib>Swidan, Ala'aeddeen</creatorcontrib><creatorcontrib>Macdonald, Charles L. B.</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kosnik, Stephanie C.</au><au>Binder, Justin F.</au><au>Nascimento, Maxemilian C.</au><au>Swidan, Ala'aeddeen</au><au>Macdonald, Charles L. B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diphosphoniodiphosphene Formation by Transition Metal Insertion into a Triphosphenium Zwitterion</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2019-01-24</date><risdate>2019</risdate><volume>25</volume><issue>5</issue><spage>1208</spage><epage>1211</epage><pages>1208-1211</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>Treatment of two equivalents of the triphosphenium zwitterion L with sources of Ni0 and Pd0 form the mononuclear η2‐diphosphoniodiphosphene complexes 1 and 2. The reaction between L and [FeCp(CO)2]2 results in the binuclear μ‐η1:η1‐diphosphoniodiphosphene iron complex 3, which features an alternative bonding motif of the diphosphoniodiphosphene unit. The formation of these species has been confirmed by spectroscopic methods and single‐crystal X‐ray diffraction analysis, and their electronic structures have been elucidated using computational methods.
A diphosphoniodiphosphene is unexpectedly formed by insertion of Ni0, Pd0, and FeI into the P−P bonds of a triphosphenium zwitterion, giving rise to structurally confirmed μ2‐bound monometallic or μ‐η1:η1‐bimetallic species.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>30468552</pmid><doi>10.1002/chem.201805711</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-0574-1524</orcidid></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Chemistry Computer applications Crystal structure diphosphene insertion Iron oligophosphorus Palladium phosphorus Transition metals triphosphenium X-ray diffraction Zwitterions |
| title | Diphosphoniodiphosphene Formation by Transition Metal Insertion into a Triphosphenium Zwitterion |
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