Glucosylation of benzyl alcohols by the cultured suspension cells of Nicotiana tabacum and Catharanthus roseus

The cultured cells of Nicotiana tabacum (white cells) converted regioselectively exogenous 2-, 3-, and 4-hydroxybenzyl alcohols into corresponding hydroxybenzyl-β- d-glucopyranoside. ( RS)-1-Phenylethanol having chiral center in its substituent was also glucosylated to give 1-phenylethyl-β- d-glucop...

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Veröffentlicht in:Journal of molecular catalysis. B, Enzymatic Enzymatic, 1999-01, Vol.6 (1), p.67-73
Hauptverfasser: Hirata, Toshifumi, Koya, Kazuhiko, Sarfo, Kwabena J., Shimoda, Kei, Ito, Diana I., Izumi, Shunsuke, Ohta, Shinji, Lee, Ym Sook
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container_end_page 73
container_issue 1
container_start_page 67
container_title Journal of molecular catalysis. B, Enzymatic
container_volume 6
creator Hirata, Toshifumi
Koya, Kazuhiko
Sarfo, Kwabena J.
Shimoda, Kei
Ito, Diana I.
Izumi, Shunsuke
Ohta, Shinji
Lee, Ym Sook
description The cultured cells of Nicotiana tabacum (white cells) converted regioselectively exogenous 2-, 3-, and 4-hydroxybenzyl alcohols into corresponding hydroxybenzyl-β- d-glucopyranoside. ( RS)-1-Phenylethanol having chiral center in its substituent was also glucosylated to give 1-phenylethyl-β- d-glucopyranoside by the cultured cells of N. tabacum (white and green cells) and Catharanthus roseus. The glucosylation with the green cells of N. tabacum occurred enantioselectively to give the glucoside of ( S)-alcohol preferentially, while the glucosylation with the white cells of N. tabacum and the C. roseus cells gave preferentially the glucoside of ( R)-alcohol.
doi_str_mv 10.1016/S1381-1177(98)00127-1
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( RS)-1-Phenylethanol having chiral center in its substituent was also glucosylated to give 1-phenylethyl-β- d-glucopyranoside by the cultured cells of N. tabacum (white and green cells) and Catharanthus roseus. The glucosylation with the green cells of N. tabacum occurred enantioselectively to give the glucoside of ( S)-alcohol preferentially, while the glucosylation with the white cells of N. tabacum and the C. roseus cells gave preferentially the glucoside of ( R)-alcohol.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/S1381-1177(98)00127-1</doi><tpages>7</tpages></addata></record>
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1873-3158
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source Elsevier ScienceDirect Journals
subjects 1-Phenylethanol
Bioconversion
Bioconversions. Hemisynthesis
Biological and medical sciences
Biotechnology
Catharanthus roseus
Cell culture
Chiral discrimination
Cultured cells
Enzymes
Fundamental and applied biological sciences. Psychology
Glucosylation
Hydroxybenzyl alcohol
Methods. Procedures. Technologies
Nicotiana tabacum
title Glucosylation of benzyl alcohols by the cultured suspension cells of Nicotiana tabacum and Catharanthus roseus
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