Manifestations of Weak O–H···F Hydrogen Bonding in M(H2O) n (B12F12) Salt Hydrates: Unusually Sharp Fourier Transform Infrared ν(OH) Bands and Latent Porosity (M = Mg–Ba, Co, Ni, Zn)

Eight M­(H2O) n (Z) salt hydrates were characterized by single-crystal X-ray diffraction (Z2– = B12F12 2–): M = Ca, Sr, n = 7; M = Mg, Co, Ni, Zn, n = 6; M = Ba, n = 4, 5. Weak O–H···F hydrogen bonding between the M­(H2O) n 2+ cations and Z2– resulted in room-temperature Fourier transform infrared (...

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Veröffentlicht in:	Inorganic chemistry 2018-12, Vol.57 (23), p.14983-15000
Hauptverfasser:	Lacroix, Matthew R, Bukovsky, Eric V, Lozinšek, Matic, Folsom, Travis C, Newell, Brian S, Liu, Yong, Peryshkov, Dmitry V, Strauss, Steven H
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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