Improvement of biodiesel production based on the application of ultrasound: Monitoring of the procedure by FTIR spectroscopy
A novel application of ultrasounds is presented for the improvement of the efficiency of the production of FAME (or biodiesel) from materials not used so far for this purpose, such as seed cakes. The novelty of this work is the introduction of in situ derivatization assisted by ultrasounds (ultrason...
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| Veröffentlicht in: | Journal of the American Oil Chemists' Society 2006-01, Vol.83 (1), p.53-57 |
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| container_title | Journal of the American Oil Chemists' Society |
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| creator | Siatis, N. G. Kimbaris, A. C. Pappas, C. S. Tarantilis, P. A. Polissiou, M. G. |
| description | A novel application of ultrasounds is presented for the improvement of the efficiency of the production of FAME (or biodiesel) from materials not used so far for this purpose, such as seed cakes. The novelty of this work is the introduction of in situ derivatization assisted by ultrasounds (ultrasonically assisted extraction transesterification) for biodiesel production. Thus, the TG contained in solid material are extracted and immediately transesterified in a methanolic solution of 1 M NaOH in an ultrasonic field. The total yield of FAME from seeds that contain TG is greatly increased in most instances. In the seeds use in this work yields were increased from 46 to 85.5% for cotton, 67.2 to 93% for sunflower, and 43.2 to 83.5% for sesame. An FTIR methodology was developed to determine the percentage of FAME in the n‐hexane layer of the reaction and thus, to monitor the reaction process. Overall advantages of the proposed methodology include the elimination of saponification, low reaction time, milder reaction conditions, and higher FAME yields. |
| doi_str_mv | 10.1007/s11746-006-1175-1 |
| format | Article |
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G. ; Kimbaris, A. C. ; Pappas, C. S. ; Tarantilis, P. A. ; Polissiou, M. G.</creator><creatorcontrib>Siatis, N. G. ; Kimbaris, A. C. ; Pappas, C. S. ; Tarantilis, P. A. ; Polissiou, M. G.</creatorcontrib><description>A novel application of ultrasounds is presented for the improvement of the efficiency of the production of FAME (or biodiesel) from materials not used so far for this purpose, such as seed cakes. The novelty of this work is the introduction of in situ derivatization assisted by ultrasounds (ultrasonically assisted extraction transesterification) for biodiesel production. Thus, the TG contained in solid material are extracted and immediately transesterified in a methanolic solution of 1 M NaOH in an ultrasonic field. The total yield of FAME from seeds that contain TG is greatly increased in most instances. In the seeds use in this work yields were increased from 46 to 85.5% for cotton, 67.2 to 93% for sunflower, and 43.2 to 83.5% for sesame. An FTIR methodology was developed to determine the percentage of FAME in the n‐hexane layer of the reaction and thus, to monitor the reaction process. Overall advantages of the proposed methodology include the elimination of saponification, low reaction time, milder reaction conditions, and higher FAME yields.</description><identifier>ISSN: 0003-021X</identifier><identifier>EISSN: 1558-9331</identifier><identifier>DOI: 10.1007/s11746-006-1175-1</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer‐Verlag</publisher><subject>Alkali‐catalyzed transesterification ; Biodiesel fuels ; biodiesel production monitoring ; Biological and medical sciences ; Extraction processes ; FAME ; Fat industries ; FIIR spectroscopy ; Food industries ; Fundamental and applied biological sciences. Psychology ; Helianthus ; in situ transes‐terfication ; seed cakes ; simultaneous extraction transesterification ; Sodium hydroxide ; Spectrum analysis ; Ultrasonic imaging ; ultrasounds</subject><ispartof>Journal of the American Oil Chemists' Society, 2006-01, Vol.83 (1), p.53-57</ispartof><rights>2006 American Oil Chemists' Society (AOCS)</rights><rights>2006 INIST-CNRS</rights><rights>Copyright AOCS Press Jan 2006</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4243-ed2f60fe60c1381359096505af2a4d21f53d255e077cf3fef27925f354f65d033</citedby><cites>FETCH-LOGICAL-c4243-ed2f60fe60c1381359096505af2a4d21f53d255e077cf3fef27925f354f65d033</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1007%2Fs11746-006-1175-1$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1007%2Fs11746-006-1175-1$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,4024,27923,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17535125$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Siatis, N. G.</creatorcontrib><creatorcontrib>Kimbaris, A. C.</creatorcontrib><creatorcontrib>Pappas, C. S.</creatorcontrib><creatorcontrib>Tarantilis, P. A.</creatorcontrib><creatorcontrib>Polissiou, M. G.</creatorcontrib><title>Improvement of biodiesel production based on the application of ultrasound: Monitoring of the procedure by FTIR spectroscopy</title><title>Journal of the American Oil Chemists' Society</title><description>A novel application of ultrasounds is presented for the improvement of the efficiency of the production of FAME (or biodiesel) from materials not used so far for this purpose, such as seed cakes. The novelty of this work is the introduction of in situ derivatization assisted by ultrasounds (ultrasonically assisted extraction transesterification) for biodiesel production. Thus, the TG contained in solid material are extracted and immediately transesterified in a methanolic solution of 1 M NaOH in an ultrasonic field. The total yield of FAME from seeds that contain TG is greatly increased in most instances. In the seeds use in this work yields were increased from 46 to 85.5% for cotton, 67.2 to 93% for sunflower, and 43.2 to 83.5% for sesame. An FTIR methodology was developed to determine the percentage of FAME in the n‐hexane layer of the reaction and thus, to monitor the reaction process. Overall advantages of the proposed methodology include the elimination of saponification, low reaction time, milder reaction conditions, and higher FAME yields.</description><subject>Alkali‐catalyzed transesterification</subject><subject>Biodiesel fuels</subject><subject>biodiesel production monitoring</subject><subject>Biological and medical sciences</subject><subject>Extraction processes</subject><subject>FAME</subject><subject>Fat industries</subject><subject>FIIR spectroscopy</subject><subject>Food industries</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Helianthus</subject><subject>in situ transes‐terfication</subject><subject>seed cakes</subject><subject>simultaneous extraction transesterification</subject><subject>Sodium hydroxide</subject><subject>Spectrum analysis</subject><subject>Ultrasonic imaging</subject><subject>ultrasounds</subject><issn>0003-021X</issn><issn>1558-9331</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNqFkdFrFDEQxoMoeFb_AN-CYN-2TpKdzZ1v5WjtQaWgFXwLuWSiKXubbbKrHPjHm_MKhb74lMnM7_uY5GPsrYAzAaA_FCF02zUAXVMrbMQzthCIy2allHjOFgCgGpDi-0v2qpS7el0qiQv2Z7Mbc_pFOxomngLfxuQjFep5bfvZTTENfGsLeV6L6SdxO459dPbfoArmfsq2pHnwH_nnNMQp5Tj8OEwOcDVx5OdMfLvnl7ebL7yM5Kacikvj_jV7EWxf6M3DecK-XV7crq-a65tPm_X5deNa2aqGvAwdBOrACbUUClew6hDQBmlbL0VA5SUigdYuqEBB6pXEoLANHXpQ6oSdHn3rOvczlcnsYnHU93agNBcjhVJd20EF3z0B79Kch7qbkRqh1fWTKySOkKvPKJmCGXPc2bw3AswhDHMMw9QwzCEMI6rm_YOxLc72IdvBxfIo1KhQSKycPnK_Y0_7_xub85v1VwBU6i-OxZrd</recordid><startdate>200601</startdate><enddate>200601</enddate><creator>Siatis, N. 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G. ; Kimbaris, A. C. ; Pappas, C. S. ; Tarantilis, P. A. ; Polissiou, M. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4243-ed2f60fe60c1381359096505af2a4d21f53d255e077cf3fef27925f354f65d033</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Alkali‐catalyzed transesterification</topic><topic>Biodiesel fuels</topic><topic>biodiesel production monitoring</topic><topic>Biological and medical sciences</topic><topic>Extraction processes</topic><topic>FAME</topic><topic>Fat industries</topic><topic>FIIR spectroscopy</topic><topic>Food industries</topic><topic>Fundamental and applied biological sciences. 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Thus, the TG contained in solid material are extracted and immediately transesterified in a methanolic solution of 1 M NaOH in an ultrasonic field. The total yield of FAME from seeds that contain TG is greatly increased in most instances. In the seeds use in this work yields were increased from 46 to 85.5% for cotton, 67.2 to 93% for sunflower, and 43.2 to 83.5% for sesame. An FTIR methodology was developed to determine the percentage of FAME in the n‐hexane layer of the reaction and thus, to monitor the reaction process. Overall advantages of the proposed methodology include the elimination of saponification, low reaction time, milder reaction conditions, and higher FAME yields.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer‐Verlag</pub><doi>10.1007/s11746-006-1175-1</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Alkali‐catalyzed transesterification Biodiesel fuels biodiesel production monitoring Biological and medical sciences Extraction processes FAME Fat industries FIIR spectroscopy Food industries Fundamental and applied biological sciences. Psychology Helianthus in situ transes‐terfication seed cakes simultaneous extraction transesterification Sodium hydroxide Spectrum analysis Ultrasonic imaging ultrasounds |
| title | Improvement of biodiesel production based on the application of ultrasound: Monitoring of the procedure by FTIR spectroscopy |
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