Polyethylene Glycols for the Dispersion Development of Graphene in an Aqueous Surfactant Solution Studied by Affinity Capillary Electrophoresis

Water-soluble nonionic polymers of polyethylene glycol (PEG), poly(vinyl alcohol) (PVA), and polyvinylpyrrolidone (PVP) were examined to develop the dispersion of graphene in an aqueous surfactant solution. Sodium dodecylbenzenesulfonate was used as an anionic surfactant to disperse graphene in an a...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Analytical Sciences 2019/03/10, Vol.35(3), pp.307-313
Hauptverfasser: TAKAYANAGI, Toshio, BECCHAKU, Yuta, TOMIYAMA, Yuki, KURASHINA, Masashi, MIZUGUCHI, Hitoshi
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 313
container_issue 3
container_start_page 307
container_title Analytical Sciences
container_volume 35
creator TAKAYANAGI, Toshio
BECCHAKU, Yuta
TOMIYAMA, Yuki
KURASHINA, Masashi
MIZUGUCHI, Hitoshi
description Water-soluble nonionic polymers of polyethylene glycol (PEG), poly(vinyl alcohol) (PVA), and polyvinylpyrrolidone (PVP) were examined to develop the dispersion of graphene in an aqueous surfactant solution. Sodium dodecylbenzenesulfonate was used as an anionic surfactant to disperse graphene in an aqueous solution and to give negative charge on it. The dispersion of graphene was monitored through the electropherograms in affinity capillary electrophoresis; a broad peak for the dispersed graphene and shot signals for the aggregated one. When PEG was added in the separation buffer as an affinity reagent, the number of the shot signals in the electropherogram was reduced; PEG can develop the dispersion of graphene in an aqueous surfactant solution. The dispersion was also developed with PVP or PVA. The effective electrophoretic mobility of the dispersed graphene was reduced by using the polymer as an affinity reagent. The result suggested that the anionic surfactant on the graphene surface was competitively substituted with the nonionic polymer. The degree of the decrease in the effective electrophoretic mobility was larger with PEG with a high-molecular mass. The broad peak of the dispersed graphene got narrower by the addition of PEG, and the number of theoretical plates was improved.
doi_str_mv 10.2116/analsci.18P433
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2132290894</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2230828021</sourcerecordid><originalsourceid>FETCH-LOGICAL-c702t-bcc170d99a62ed7f9d84715dee75c6a8fc05b93b7f4df3126547a36102b6dceb3</originalsourceid><addsrcrecordid>eNp1kUuL2zAUhUVp6WTSbrssgm66cUYPP5chmWYKAx1IuzayfDVWUCRXkgf8K_qXa-M0hUI30uJ-5-geHYQ-ULJhlOZ3wgoTpN7Q8inl_BVaUZ6WCWNp_hqtSEVJkvOU3KDbEE6EUFYy9hbdcJLSnOblCv16cmaE2I0GLOCDGaUzASvncewA73XowQftLN7DCxjXn8FG7BQ-eNF3s0RbLCze_hzADQEfB6-EjGKCjs4McVYe49BqaHEz4q1S2uo44p3otTHCj_jegIze9Z3zEHR4h96oKRG8v9xr9OPL_ffdQ_L47fB1t31MZEFYTBopaUHaqhI5g7ZQVVumBc1agCKTuSiVJFlT8aZQaas4ZXmWFoLnlLAmbyU0fI0-L769d9PuIdZnHSRMO9k5SM0oZ6wiZZVO6Kd_0JMb_PzvNWOclKwkE71Gm4WS3oXgQdW91-cpYU1JPVdVX6qql6omwceL7dCcob3if7qZgLsFCNPIPoP_--5_LfeL4hSieIarpfBRSwNXnGc1n49Fdh3LTvgaLP8Nfvi8dA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2230828021</pqid></control><display><type>article</type><title>Polyethylene Glycols for the Dispersion Development of Graphene in an Aqueous Surfactant Solution Studied by Affinity Capillary Electrophoresis</title><source>J-STAGE Free</source><source>Freely Accessible Japanese Titles</source><source>EZB-FREE-00999 freely available EZB journals</source><source>Free Full-Text Journals in Chemistry</source><source>SpringerLink Journals - AutoHoldings</source><creator>TAKAYANAGI, Toshio ; BECCHAKU, Yuta ; TOMIYAMA, Yuki ; KURASHINA, Masashi ; MIZUGUCHI, Hitoshi</creator><creatorcontrib>TAKAYANAGI, Toshio ; BECCHAKU, Yuta ; TOMIYAMA, Yuki ; KURASHINA, Masashi ; MIZUGUCHI, Hitoshi</creatorcontrib><description>Water-soluble nonionic polymers of polyethylene glycol (PEG), poly(vinyl alcohol) (PVA), and polyvinylpyrrolidone (PVP) were examined to develop the dispersion of graphene in an aqueous surfactant solution. Sodium dodecylbenzenesulfonate was used as an anionic surfactant to disperse graphene in an aqueous solution and to give negative charge on it. The dispersion of graphene was monitored through the electropherograms in affinity capillary electrophoresis; a broad peak for the dispersed graphene and shot signals for the aggregated one. When PEG was added in the separation buffer as an affinity reagent, the number of the shot signals in the electropherogram was reduced; PEG can develop the dispersion of graphene in an aqueous surfactant solution. The dispersion was also developed with PVP or PVA. The effective electrophoretic mobility of the dispersed graphene was reduced by using the polymer as an affinity reagent. The result suggested that the anionic surfactant on the graphene surface was competitively substituted with the nonionic polymer. The degree of the decrease in the effective electrophoretic mobility was larger with PEG with a high-molecular mass. The broad peak of the dispersed graphene got narrower by the addition of PEG, and the number of theoretical plates was improved.</description><identifier>ISSN: 0910-6340</identifier><identifier>EISSN: 1348-2246</identifier><identifier>DOI: 10.2116/analsci.18P433</identifier><identifier>PMID: 30416168</identifier><language>eng</language><publisher>Singapore: The Japan Society for Analytical Chemistry</publisher><subject>Affinity ; affinity capillary electrophoresis ; Alcohols ; Analytical Chemistry ; Aqueous solutions ; Capillary electrophoresis ; Chemistry ; Dispersion ; effective electrophoretic mobility ; Electrophoresis ; Electrophoretic mobility ; Graphene ; Mobility ; number of theoretical plates ; Polyethylene glycol ; Polymers ; Polyvinyl alcohol ; Polyvinylpyrrolidone ; Reagents ; Sodium ; Sodium dodecylbenzenesulfonate ; Surfactants</subject><ispartof>Analytical Sciences, 2019/03/10, Vol.35(3), pp.307-313</ispartof><rights>2019 by The Japan Society for Analytical Chemistry</rights><rights>The Japan Society for Analytical Chemistry 2019</rights><rights>Copyright Japan Science and Technology Agency 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c702t-bcc170d99a62ed7f9d84715dee75c6a8fc05b93b7f4df3126547a36102b6dceb3</citedby><cites>FETCH-LOGICAL-c702t-bcc170d99a62ed7f9d84715dee75c6a8fc05b93b7f4df3126547a36102b6dceb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.2116/analsci.18P433$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.2116/analsci.18P433$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,1881,27923,27924,41487,42556,51318</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30416168$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>TAKAYANAGI, Toshio</creatorcontrib><creatorcontrib>BECCHAKU, Yuta</creatorcontrib><creatorcontrib>TOMIYAMA, Yuki</creatorcontrib><creatorcontrib>KURASHINA, Masashi</creatorcontrib><creatorcontrib>MIZUGUCHI, Hitoshi</creatorcontrib><title>Polyethylene Glycols for the Dispersion Development of Graphene in an Aqueous Surfactant Solution Studied by Affinity Capillary Electrophoresis</title><title>Analytical Sciences</title><addtitle>ANAL. SCI</addtitle><addtitle>Anal Sci</addtitle><description>Water-soluble nonionic polymers of polyethylene glycol (PEG), poly(vinyl alcohol) (PVA), and polyvinylpyrrolidone (PVP) were examined to develop the dispersion of graphene in an aqueous surfactant solution. Sodium dodecylbenzenesulfonate was used as an anionic surfactant to disperse graphene in an aqueous solution and to give negative charge on it. The dispersion of graphene was monitored through the electropherograms in affinity capillary electrophoresis; a broad peak for the dispersed graphene and shot signals for the aggregated one. When PEG was added in the separation buffer as an affinity reagent, the number of the shot signals in the electropherogram was reduced; PEG can develop the dispersion of graphene in an aqueous surfactant solution. The dispersion was also developed with PVP or PVA. The effective electrophoretic mobility of the dispersed graphene was reduced by using the polymer as an affinity reagent. The result suggested that the anionic surfactant on the graphene surface was competitively substituted with the nonionic polymer. The degree of the decrease in the effective electrophoretic mobility was larger with PEG with a high-molecular mass. The broad peak of the dispersed graphene got narrower by the addition of PEG, and the number of theoretical plates was improved.</description><subject>Affinity</subject><subject>affinity capillary electrophoresis</subject><subject>Alcohols</subject><subject>Analytical Chemistry</subject><subject>Aqueous solutions</subject><subject>Capillary electrophoresis</subject><subject>Chemistry</subject><subject>Dispersion</subject><subject>effective electrophoretic mobility</subject><subject>Electrophoresis</subject><subject>Electrophoretic mobility</subject><subject>Graphene</subject><subject>Mobility</subject><subject>number of theoretical plates</subject><subject>Polyethylene glycol</subject><subject>Polymers</subject><subject>Polyvinyl alcohol</subject><subject>Polyvinylpyrrolidone</subject><subject>Reagents</subject><subject>Sodium</subject><subject>Sodium dodecylbenzenesulfonate</subject><subject>Surfactants</subject><issn>0910-6340</issn><issn>1348-2246</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kUuL2zAUhUVp6WTSbrssgm66cUYPP5chmWYKAx1IuzayfDVWUCRXkgf8K_qXa-M0hUI30uJ-5-geHYQ-ULJhlOZ3wgoTpN7Q8inl_BVaUZ6WCWNp_hqtSEVJkvOU3KDbEE6EUFYy9hbdcJLSnOblCv16cmaE2I0GLOCDGaUzASvncewA73XowQftLN7DCxjXn8FG7BQ-eNF3s0RbLCze_hzADQEfB6-EjGKCjs4McVYe49BqaHEz4q1S2uo44p3otTHCj_jegIze9Z3zEHR4h96oKRG8v9xr9OPL_ffdQ_L47fB1t31MZEFYTBopaUHaqhI5g7ZQVVumBc1agCKTuSiVJFlT8aZQaas4ZXmWFoLnlLAmbyU0fI0-L769d9PuIdZnHSRMO9k5SM0oZ6wiZZVO6Kd_0JMb_PzvNWOclKwkE71Gm4WS3oXgQdW91-cpYU1JPVdVX6qql6omwceL7dCcob3if7qZgLsFCNPIPoP_--5_LfeL4hSieIarpfBRSwNXnGc1n49Fdh3LTvgaLP8Nfvi8dA</recordid><startdate>20190310</startdate><enddate>20190310</enddate><creator>TAKAYANAGI, Toshio</creator><creator>BECCHAKU, Yuta</creator><creator>TOMIYAMA, Yuki</creator><creator>KURASHINA, Masashi</creator><creator>MIZUGUCHI, Hitoshi</creator><general>The Japan Society for Analytical Chemistry</general><general>Springer Nature Singapore</general><general>Japan Science and Technology Agency</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope><scope>P64</scope><scope>7X8</scope></search><sort><creationdate>20190310</creationdate><title>Polyethylene Glycols for the Dispersion Development of Graphene in an Aqueous Surfactant Solution Studied by Affinity Capillary Electrophoresis</title><author>TAKAYANAGI, Toshio ; BECCHAKU, Yuta ; TOMIYAMA, Yuki ; KURASHINA, Masashi ; MIZUGUCHI, Hitoshi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c702t-bcc170d99a62ed7f9d84715dee75c6a8fc05b93b7f4df3126547a36102b6dceb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Affinity</topic><topic>affinity capillary electrophoresis</topic><topic>Alcohols</topic><topic>Analytical Chemistry</topic><topic>Aqueous solutions</topic><topic>Capillary electrophoresis</topic><topic>Chemistry</topic><topic>Dispersion</topic><topic>effective electrophoretic mobility</topic><topic>Electrophoresis</topic><topic>Electrophoretic mobility</topic><topic>Graphene</topic><topic>Mobility</topic><topic>number of theoretical plates</topic><topic>Polyethylene glycol</topic><topic>Polymers</topic><topic>Polyvinyl alcohol</topic><topic>Polyvinylpyrrolidone</topic><topic>Reagents</topic><topic>Sodium</topic><topic>Sodium dodecylbenzenesulfonate</topic><topic>Surfactants</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>TAKAYANAGI, Toshio</creatorcontrib><creatorcontrib>BECCHAKU, Yuta</creatorcontrib><creatorcontrib>TOMIYAMA, Yuki</creatorcontrib><creatorcontrib>KURASHINA, Masashi</creatorcontrib><creatorcontrib>MIZUGUCHI, Hitoshi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical Sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>TAKAYANAGI, Toshio</au><au>BECCHAKU, Yuta</au><au>TOMIYAMA, Yuki</au><au>KURASHINA, Masashi</au><au>MIZUGUCHI, Hitoshi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polyethylene Glycols for the Dispersion Development of Graphene in an Aqueous Surfactant Solution Studied by Affinity Capillary Electrophoresis</atitle><jtitle>Analytical Sciences</jtitle><stitle>ANAL. SCI</stitle><addtitle>Anal Sci</addtitle><date>2019-03-10</date><risdate>2019</risdate><volume>35</volume><issue>3</issue><spage>307</spage><epage>313</epage><pages>307-313</pages><issn>0910-6340</issn><eissn>1348-2246</eissn><abstract>Water-soluble nonionic polymers of polyethylene glycol (PEG), poly(vinyl alcohol) (PVA), and polyvinylpyrrolidone (PVP) were examined to develop the dispersion of graphene in an aqueous surfactant solution. Sodium dodecylbenzenesulfonate was used as an anionic surfactant to disperse graphene in an aqueous solution and to give negative charge on it. The dispersion of graphene was monitored through the electropherograms in affinity capillary electrophoresis; a broad peak for the dispersed graphene and shot signals for the aggregated one. When PEG was added in the separation buffer as an affinity reagent, the number of the shot signals in the electropherogram was reduced; PEG can develop the dispersion of graphene in an aqueous surfactant solution. The dispersion was also developed with PVP or PVA. The effective electrophoretic mobility of the dispersed graphene was reduced by using the polymer as an affinity reagent. The result suggested that the anionic surfactant on the graphene surface was competitively substituted with the nonionic polymer. The degree of the decrease in the effective electrophoretic mobility was larger with PEG with a high-molecular mass. The broad peak of the dispersed graphene got narrower by the addition of PEG, and the number of theoretical plates was improved.</abstract><cop>Singapore</cop><pub>The Japan Society for Analytical Chemistry</pub><pmid>30416168</pmid><doi>10.2116/analsci.18P433</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0910-6340
ispartof Analytical Sciences, 2019/03/10, Vol.35(3), pp.307-313
issn 0910-6340
1348-2246
language eng
recordid cdi_proquest_miscellaneous_2132290894
source J-STAGE Free; Freely Accessible Japanese Titles; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry; SpringerLink Journals - AutoHoldings
subjects Affinity
affinity capillary electrophoresis
Alcohols
Analytical Chemistry
Aqueous solutions
Capillary electrophoresis
Chemistry
Dispersion
effective electrophoretic mobility
Electrophoresis
Electrophoretic mobility
Graphene
Mobility
number of theoretical plates
Polyethylene glycol
Polymers
Polyvinyl alcohol
Polyvinylpyrrolidone
Reagents
Sodium
Sodium dodecylbenzenesulfonate
Surfactants
title Polyethylene Glycols for the Dispersion Development of Graphene in an Aqueous Surfactant Solution Studied by Affinity Capillary Electrophoresis
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-10T21%3A53%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Polyethylene%20Glycols%20for%20the%20Dispersion%20Development%20of%20Graphene%20in%20an%20Aqueous%20Surfactant%20Solution%20Studied%20by%20Affinity%20Capillary%20Electrophoresis&rft.jtitle=Analytical%20Sciences&rft.au=TAKAYANAGI,%20Toshio&rft.date=2019-03-10&rft.volume=35&rft.issue=3&rft.spage=307&rft.epage=313&rft.pages=307-313&rft.issn=0910-6340&rft.eissn=1348-2246&rft_id=info:doi/10.2116/analsci.18P433&rft_dat=%3Cproquest_cross%3E2230828021%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2230828021&rft_id=info:pmid/30416168&rfr_iscdi=true