Preferential Photoreaction in a Porous Crystal, Metal–Macrocycle Framework: PdII-Mediated Olefin Migration over [2+2] Cycloaddition

A nanosized confined space with well-defined functional surfaces has great potential to control the efficiency and selectivity of catalytic reactions. Herein we report that a 1,6-diene, which normally forms an intramolecular [2+2] cycloadduct under photoirradiation, preferentially undergoes a photoi...

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Veröffentlicht in:	Journal of the American Chemical Society 2018-12, Vol.140 (48), p.16610-16614
Hauptverfasser:	Yonezawa, Hirotaka, Tashiro, Shohei, Shiraogawa, Takafumi, Ehara, Masahiro, Shimada, Rintaro, Ozawa, Takeaki, Shionoya, Mitsuhiko
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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