Atmospheric‐pressure ionization mass‐spectrometric analysis of new anionic surfactants: The alkylpolyglucoside esters
Atmospheric‐pressure ionization mass spectrometry has been successfully applied to characterization of a new class of anionic surfactants, the alkylpolyglucoside esters of sulfosuccinic, citric and tartaric acid. Complex mixtures of final and intermediate products were injected directly into the ion...
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| Veröffentlicht in: | Journal of the American Oil Chemists' Society 1995-01, Vol.72 (1), p.1-9 |
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| container_title | Journal of the American Oil Chemists' Society |
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| creator | Facino, Roberto Maffei Carini, Marina Depta, Gabriele Bernardi, Paolo Casetta, Bruno |
| description | Atmospheric‐pressure ionization mass spectrometry has been successfully applied to characterization of a new class of anionic surfactants, the alkylpolyglucoside esters of sulfosuccinic, citric and tartaric acid. Complex mixtures of final and intermediate products were injected directly into the ion source without prior chromatographic separation. The constituents were identified on the basis of quasi‐molecular ions: cationized ions or solute‐solute cluster ions in positive‐ion mode, and deprotonated ions in negative‐ion mode. The mass‐spectrometric data show that all three final products contain one nonionic and two different types of anionic surfactants. The “real time,” highly sensitive mass‐spectrometric approach proposed here is well suited for quality control testing of tensides, to ensure the safety of the final product, and for the validation of the manufacturing process, because it is able to identify the individual components of the mixture. |
| doi_str_mv | 10.1007/BF02635771 |
| format | Article |
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Complex mixtures of final and intermediate products were injected directly into the ion source without prior chromatographic separation. The constituents were identified on the basis of quasi‐molecular ions: cationized ions or solute‐solute cluster ions in positive‐ion mode, and deprotonated ions in negative‐ion mode. The mass‐spectrometric data show that all three final products contain one nonionic and two different types of anionic surfactants. The “real time,” highly sensitive mass‐spectrometric approach proposed here is well suited for quality control testing of tensides, to ensure the safety of the final product, and for the validation of the manufacturing process, because it is able to identify the individual components of the mixture.</description><identifier>ISSN: 0003-021X</identifier><identifier>EISSN: 1558-9331</identifier><identifier>DOI: 10.1007/BF02635771</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer‐Verlag</publisher><subject>Analytical chemistry ; Anionic surfactants ; APG esters ; API mass spectrometry ; Chemistry ; direct characterization ; Exact sciences and technology ; quality control testing strategies ; raw materials ; Spectrometric and optical methods</subject><ispartof>Journal of the American Oil Chemists' Society, 1995-01, Vol.72 (1), p.1-9</ispartof><rights>1995 American Oil Chemists' Society (AOCS)</rights><rights>1995 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3301-4188f6214295aee4db71f4aa624e8fad97ea04998c60b1472c7ea0dd47ca29073</citedby><cites>FETCH-LOGICAL-c3301-4188f6214295aee4db71f4aa624e8fad97ea04998c60b1472c7ea0dd47ca29073</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4010,27900,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3437617$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Facino, Roberto Maffei</creatorcontrib><creatorcontrib>Carini, Marina</creatorcontrib><creatorcontrib>Depta, Gabriele</creatorcontrib><creatorcontrib>Bernardi, Paolo</creatorcontrib><creatorcontrib>Casetta, Bruno</creatorcontrib><title>Atmospheric‐pressure ionization mass‐spectrometric analysis of new anionic surfactants: The alkylpolyglucoside esters</title><title>Journal of the American Oil Chemists' Society</title><description>Atmospheric‐pressure ionization mass spectrometry has been successfully applied to characterization of a new class of anionic surfactants, the alkylpolyglucoside esters of sulfosuccinic, citric and tartaric acid. 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| issn | 0003-021X 1558-9331 |
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| source | SpringerLink Journals |
| subjects | Analytical chemistry Anionic surfactants APG esters API mass spectrometry Chemistry direct characterization Exact sciences and technology quality control testing strategies raw materials Spectrometric and optical methods |
| title | Atmospheric‐pressure ionization mass‐spectrometric analysis of new anionic surfactants: The alkylpolyglucoside esters |
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