Interplay between Substrate and Proton Donor Coordination in Reductions of Carbonyls by SmI2–Water Through Proton-Coupled Electron-Transfer

The reduction of a carbonyl by SmI2–water is the first step in a range of reactions of synthetic importance. Although the reduction is often proposed to proceed through an initial stepwise electron-transfer–proton-transfer (ET-PT), recent work has shown that carbonyls and related functional groups a...

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Veröffentlicht in:	Journal of the American Chemical Society 2018-11, Vol.140 (45), p.15342-15352
Hauptverfasser:	Chciuk, Tesia V, Anderson, William R
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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