A rapid construction of the ABC tricyclic skeleton of malabanone A

A rapid construction of the ABC tricyclic skeleton of malabanone A

The construction of the ABC tricyclic skeleton of malabanone A with the required 4 stereocenters was accomplished in a concise route starting from R-carvone. The synthesis featured an intramolecular [3 + 2] cycloaddition reaction to assemble its A ring and an intramolecular Diels-Alder reaction to c...

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Veröffentlicht in:Organic & biomolecular chemistry 2018-11, Vol.16 (44), p.8491-8494
Hauptverfasser: Li, Tao, Wu, Guangmiao, Feng, Shangbiao, Wang, Zemin, Xie, Xingang, She, Xuegong
Format: Artikel
Sprache:eng
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Carvone
Chemical synthesis
Construction
Crystallography
Cycloaddition
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container_end_page 8494
container_issue 44
container_start_page 8491
container_title Organic & biomolecular chemistry
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creator Li, Tao
Wu, Guangmiao
Feng, Shangbiao
Wang, Zemin
Xie, Xingang
She, Xuegong
description The construction of the ABC tricyclic skeleton of malabanone A with the required 4 stereocenters was accomplished in a concise route starting from R-carvone. The synthesis featured an intramolecular [3 + 2] cycloaddition reaction to assemble its A ring and an intramolecular Diels-Alder reaction to construct its C ring.
doi_str_mv 10.1039/c8ob02495b
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source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Carvone
Chemical synthesis
Construction
Crystallography
Cycloaddition
title A rapid construction of the ABC tricyclic skeleton of malabanone A
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